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Self-condensation of bifunctional 8-aminoquinoline-2-carbaldehyde templated by dysprosium(III) ions followed by the replacement of axial ligands with triphenylsilanol in the presence of Et3N produced two belt macrocycles complexes [Dy(L1N6)(Ph3SiO)2][ClO4] (1) and...

Boron-assisted highly symmetric lanthanide (Ln) macrocycles, (η2-catechol-μ-catecholborate)3Ln(Ph3PO)2·xC7H8 (Ln = Dy, x = 0, Dy-B-Ph3PO; Ln = Yb, x = 1, Yb-B-Ph3PO) have been achieved by one-pot reaction of Ln[N(TMS)2]3 (TMS...

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Terminal fluoride ligands generate strongly magnetic anisotropy in air-stable chiral dysprosium enantiomers supported by bulky equatorial macrocycle, exhibting typical zero-field single-molecule magnets behaviour.

Two new dimeric dysprosium(III) complexes [Dy2(HL)2(SCN)2]·2CH3CN (1) and [Dy2(HL)2(NO3)2]·2CH3CN·2H2O (2) have been assembled using the H3L multidentate ligand (H3L = 2,2'-((((2-hydroxy-5-methyl-1,3-phenylene)bis(methylene))bis((pyridin-2-ylmethyl)azanediyl))bis(methylene))diphenol). The use of different coordination anions for the two...

A pair of air-stable double-decker Dy(III) macrocyclic enantiomers featuring sole fluoride axial ligands were designed and structurally and magnetically characterized. They displayed strong intramolecular ferromagnetic coupling and two-step relaxation of...

The subcomponent self-assembly of 4,6-dihydrazinopyrimidine and o-vanillin/salicylaldehyde with different DyIII salts lead to the formation of linear Dy2 (1−3) and grid-like Dy4 (4) compounds with formulas of [Dy2L(DMF)4(NO3)4]·2DMF (1), [Dy2L2(CH3COO)4(CH3OH)2]·10H2O...