Organolead trihalide perovskites have attracted great attention due to the stunning advances in both photovoltaic and light-emitting devices. However, the photophysical properties, especially the recombination dynamics of photogenerated carriers, of this class of materials are controversial. Here we report that under an excitation level close to the working regime of solar cells, the recombination of photogenerated carriers in solution-processed methylammonium–lead–halide films is dominated by excitons weakly localized in band tail states. This scenario is evidenced by experiments of spectral-dependent luminescence decay, excitation density-dependent luminescence and frequency-dependent terahertz photoconductivity. The exciton localization effect is found to be general for several solution-processed hybrid perovskite films prepared by different methods. Our results provide insights into the charge transport and recombination mechanism in perovskite films and help to unravel their potential for high-performance optoelectronic devices.

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Based on the complementary V-shaped antenna structure, ultrathin vortex phase plates are designed to achieve the terahertz (THz) optical vortices with different topological charges. Utilizing a THz holographic imaging system, the two dimensional complex field information of the generated THz vortex beam with the topological number l=1 is directly obtained. Its far field propagation properties are analyzed in detail, including the rotation, the twist direction, and the Gouy phase shift of the vortex phase. An analytic Laguerre-Gaussian mode is used to simulate and explain the measured phenomena. The experimental and simulation results overlap each other very well.