Metasurface-based near perfect absorbers exhibit a wide range of potential applications in the fields of solar energy harvesting, thermal images and sensors due to their unique absorption regulation function. However, absorption characteristics of devices are locked by the device structure, leading to the limitation in real-time dynamic applications. In this work, we integrate the phase change material VO2 thin film into the metal-insulator-metal structured metasurface based absorber, and design a fully visible band switchable dynamically tunable absorber (DTA). By controlling the phase transition of VO2, the DTA can realize a novel switch function in the full band of visible light (400 ∼ 780 nm), with absorption contrast ranges from 42% to 60%. Furthermore, via accurate structural parameter control, the vivid cyan, magenta, and yellow pixels based on the VO2 DTA are designed and proposed in the real-time optical anti-counterfeiting, exhibiting outstanding characteristics of anti-glare interference and real-time encryption ability. The absorption spectrum and local electric field are simulated and analyzed to study the internal operation mechanism of DTA. The dynamic absorption adjustable function is attributed to the synergistic effect of insulator-metal transition of VO2 and Fabry–Pérot resonance of absorber.
Cesium lead halide perovskite nanocrystals (NCs) have attracted enormous interest in light-emitting diode, photodetector and low-threshold lasing application in terms of their unique optical and electrical performance. However, little attention has been paid to other structures associated with CsPbBr3, such as CsPb2Br5. Herein, we realize a facile method to prepare dual-phase NCs with improved stability against polar solvents by replacing conventional oleylamine with cetyltrimethyl ammonium bromide (CTAB) in the reprecipitation process. The growth of NCs can be regulated with different ratios of toluene and ethanol depending on solvent polarity, which not only obtains NCs with different sizes and morphologies, but also controls phase transition between orthorhombic CsPbBr3 and tetragonal CsPb2Br5. The photoluminescence (PL) and defect density calculated exhibit considerable solvent polarity dependence, which is ascribed to solvent polarity affecting the ability of CTAB to passivate surface defects and improve stoichiometry in the system. This new synthetic method of perovskite material will be helpful for further studies in the field of lighting and detectors.
Novel LiLa1−x−y(MoO4)2:xSm3+,yEu3+ (in short: LL1−x−yM:xSm3+,yEu3+) double molybdate red phosphors were synthesized by a solid-state reaction at as low temperature as 610 °C. The optimal doping concentration of Sm3+ in LiLa1−x(MoO4)2:xSm3+ (LL1−xM:xSm3+) phosphor is x = 0.05 and higher concentrations lead to emission quenching by the electric dipole—electric dipole mechanism. In the samples co-doped with Eu3+ ions, the absorption spectrum in the near ultraviolet and blue regions became broader and stronger than these of the Sm3+ single-doped samples. The efficient energy transfer from Sm3+ to Eu3+ was found and the energy transfer efficiency was calculated. Under the excitation at 403 nm, the chromaticity coordinates of LL0.95−yM:0.05Sm3+,yEu3+ approach to the NTSC standard values (0.670, 0.330) continuously with increasing Eu3+ doping concentration. The phosphor exhibits high luminous efficiency under near UV or blue light excitation and remarkable thermal stability. At 150 °C, the integrated emission intensity of the Eu3+ remained 85% of the initial intensity at room temperature and the activation energy is calculated to be 0.254 eV. The addition of the LL0.83M:0.05Sm3+,0.12Eu3+ red phosphors can improve the color purity and reduce the correlated color temperature of WLED lamps. Hence, LL1−x−yM:xSm3+,yEu3+ is a promising WLED red phosphor.
This paper introduces a 3500V, 15A SiC power module based on self-fabricated SiC junction field effect transistors (JFETs) and schottky barrier diodes (SBDs). The module consists of four parallel connected SiC JFETs as the switching device and four SBDs as the anti-parallel diode. Both static and dynamic performances are evaluated with this module. And a kW level boost converter is also constructed to further explore its switching capabilities. With carefully designed driver circuit, the module shows superiority of a high working frequency of 100kHz with both turn-on and turn-off time less than 150ns. Circuit efficiency at different working conditions are also evaluated in this work. This is the first demonstration of high voltage (>3.3kV) SiC JFET based power module and its circuit applications in high frequency and kW-level power converter.
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