Layered double hydroxides (LDHs) with their highly flexible and tunable chemical composition and physical properties have attracted tremendous attention in recent years. LDHs have found widespread application as catalysts, anion exchange materials, fire retardants, and nano-fillers in polymer nanocomposites. The ability to exfoliate LDHs into ultrathin nanosheets enables a range of new opportunities for multifunctional materials. In this review we summarize the current available LDH exfoliation methods. In particular, we highlight recent developments for the direct synthesis of single-layer LDH nanosheets, as well as the emerging applications of LDH nanosheets in catalyzing oxygen evolution reactions and preparing light emitting devices, supercapacitors, and flame retardant nanocomposites.
In this work, rice husk biomass was utilized as an abundant source to controllably prepare high-quality graphene quantum dots (GQDs) with a yield of ca. 15 wt %. The size, morphology, and structure of the rice-husk-derived GQDs were determined by high-resolution transmission electron microscopy, atomic force microscopy, and Raman spectroscopy. The as-fabricated GQDs can be stably dispersed in water, exhibiting bright and tunable photoluminescence. A cell viability test further confirmed that the GQDs possess excellent biocompatibility, and they can be easily adopted for cell imaging via a facile translocation into the cytoplasm. It is worth noting that mesoporous silica nanoparticles were also synthesized as a byproduct during the fabrication of GQDs. As such, our strategy achieves a comprehensive utilization of rice husks, exhibiting tremendous benefits on both the economy and environment.
Layered double hydroxide (LDH) single-layer nanosheets were traditionally prepared through a multi-step exfoliation process which is very time-consuming and of low efficiency. Herein we report the preparation of LDH single-layer nanosheets through a facile direct synthesis method. By introducing a layer growth inhibitor, one can directly synthesize LDH single-layer nanosheets instead of LDH layered compounds. The inhibitor weakens the interactions between neighboring layers, thus preventing the interlayer growth. This investigation on blocking interlayer growth by weakening interlayer interactions to obtain inorganic single-layer nanosheets opens a new route for the synthesis of 2-dimensional materials.
Functionalization strategies are powerful for generating new or enhanced properties of LDHs, offering unique perspectives and advantages for preparing novel materials.
Polypropylene (PP)/carbon nanotubes (CNTs) nanocomposites were prepared by coating CNTs on the surface of gelated/swollen soft PP pellets. The electrical conductivity (σ) studies revealed a percolation threshold of only 0.3 wt %, and the electrical conductivity mechanism followed a 3-d variable range hopping (VRH) behavior. At lower processing temperature, the CNTs formed the network structure more easily, resulting in a higher σ. The fraction of γ-phase PP increased with increasing the pressing temperature. The CNTs at lower loading (0.1 wt %) served as nucleating sites and promoted the crystallization of PP. The CNTs favored the disentanglement of polymer chains and thus caused an even lower melt viscosity of nanocomposites than that of pure PP. The calculated optical band gap of CNTs was observed to increase with increasing the processing temperature, i.e., 1.55 eV for nanocomposites prepared at 120 °C and 1.70 eV prepared at 160 and 180 °C. Both the Drude model and interband transition phenomenon have been used for theoretical analysis of the real permittivity of the nanocomposites.
One of the major challenges in the circular economy relating to food packaging is the elimination of metallised film which is currently the industry standard approach to achieve the necessary gas barrier performance. Here, we report the synthesis of high aspect ratio 2D non-toxic layered double hydroxide (LDH) nanosheet dispersions using a non-toxic exfoliation method in aqueous amino acid solution. High O
2
and water vapour barrier coating films can be prepared using food safe liquid dispersions through a bar coating process. The oxygen transmission rate (OTR) of 12 μm PET coated film can be reduced from 133.5 cc·m
−2
·day
−1
to below the instrument detection limit (<0.005 cc·m
−2
·day
−1
). The water vapour transmission rate (WVTR) of the PET film can be reduced from 8.99 g·m
−2
·day
−1
to 0.04 g·m
−2
·day
−1
after coating. Most importantly, these coated films are also transparent and mechanically robust, making them suitable for flexible food packing while also offering new recycling opportunities.
Large‐diameter, tall‐stature, and big‐crown trees are the main stand structures of forests, generally contributing a large fraction of aboveground biomass, and hence play an important role in climate change mitigation strategies. Here, we hypothesized that the effects of large‐diameter, tall‐stature, and big‐crown trees overrule the effects of species richness and remaining trees attributes on aboveground biomass in tropical forests (i.e., we term the “big‐sized trees hypothesis”). Specifically, we assessed the importance of: (a) the “top 1% big‐sized trees effect” relative to species richness; (b) the “99% remaining trees effect” relative to species richness; and (c) the “top 1% big‐sized trees effect” relative to the “99% remaining trees effect” and species richness on aboveground biomass. Using environmental factor and forest inventory datasets from 712 tropical forest plots in Hainan Island of southern China, we tested several structural equation models for disentangling the relative effects of big‐sized trees, remaining trees attributes, and species richness on aboveground biomass, while considering for the full (indirect effects only) and partial (direct and indirect effects) mediation effects of climatic and soil conditions, as well as interactions between species richness and trees attributes. We found that top 1% big‐sized trees attributes strongly increased aboveground biomass (i.e., explained 55%–70% of the accounted variation) compared to species richness (2%–18%) and 99% remaining trees attributes (6%–10%). In addition, species richness increased aboveground biomass indirectly via increasing big‐sized trees but via decreasing remaining trees. Hence, we show that the “big‐sized trees effect” overrides the effects of remaining trees attributes and species richness on aboveground biomass in tropical forests. This study also indicates that big‐sized trees may be more susceptible to atmospheric drought. We argue that the effects of big‐sized trees on species richness and aboveground biomass should be tested for better understanding of the ecological mechanisms underlying forest functioning.
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