High‐voltage direct current (HVDC) and high‐voltage alternating current (HVAC) cables are the most important equipment for high‐voltage, large‐capacity and long‐distance power transmission. Electrical tree is a pre‐breakdown phenomenon leading to failure of insulation materials, and it is the major issue that threatens the safe and stable operation of HVDC and HVAC cable systems. This study summarises and analyses the achievements in the research of electrical tree for HVDC and HVAC cables. The initiation mechanisms of the electrical tree, including Maxwell electro‐mechanical stress, charge injection–extraction, charge trapping and electroluminescence theories, are elaborated for fully understanding the electrical degradation process in insulation materials. Then, the influences of the high electric field, high temperature and mechanical stress on electrical tree behaviours are discussed, and the relationship between charge transport and the electrical tree is analysed and illustrated. The suppression methods of the electrical tree are put forward by introducing inorganic and organic additives into insulation materials, and the suppression mechanisms are presented from the viewpoints of the structure‐property and microscale–macroscale relationships. Recently, the electrical tree research studies are focused on the high‐precision of initiation models, high‐dependence of multi‐physical fields and high‐efficiency of suppression methods. The achievements provide theoretical support for improving the electrical performance of insulation materials, while it is a practical problem to explore their application feasibility in HVDC and HVAC cable.

POSS (polyhedral oligomeric silsesquioxane) provides an interesting alternative nano-silica and has the potential of superior dielectric properties to restrain electrical degradation. By incorporating POSS into EPDM to suppress electrical tree, one of precursors to dielectric failure, is promising to improve the lifetime of insulation materials. This paper focuses on the electrical treeing phenomena in EPDM/OVPOSS (ethylene propylene diene monomer/octavinyl-POSS) composites based on their physicochemical properties and trap distributions. ATR-IR and SEM characteristics are investigated to observe the chemical structure and physical dispersion of EPDM/OVPOSS composites. Electrical treeing characteristics are studied by the needle-plane electrode, and the trap level distributions are characterized by surface potential decay (SPD) tests. The results show that the 3 wt% EPDM/OVPOSS is more effective to restrain the electrical tree growth than the neat EPDM in this paper. It is indicated that the EPDM/OVPOSS with a filler content of 3 wt% introduces the largest energy level and trap density of deep trapped charges, which suppress the transportation of charge carriers injected from the needle tip and further prevent the degradation of polymer molecules. The polarity effects are obvious during the electrical treeing process, which is dependent on the trap level differences between positive and negative voltage.

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Space charges tend to accumulate on the surface and at the interface of ethylene–propylene–diene terpolymer (EPDM), serving as high voltage direct current (HVDC) cable accessory insulation, which likely induces electrical field distortion and dielectric breakdown. Direct fluorination is an effective method to modify the surface characteristics of the EPDM without altering the bulk properties too much. In this paper, the surface morphology, hydrophobic properties, relative permittivity, and DC conductivity of the EPDM before and after fluorination treatment were tested. Furthermore, the surface and interface charge behaviors in the HVDC cable accessory were investigated by the pulsed electroacoustic (PEA) method, and explained from the point of view of trap distribution. The results show that fluorination helps the EPDM polymer obtain lower surface energy and relative permittivity, which is beneficial to the interface match in composite insulation systems. The lowest degree of space charge accumulation occurs in EPDM with 30 min of fluorination. After analyzing the results of the 3D potentials and the density of states (DOS) behaviors in EPDM before and after fluorination, it can be found that fluorination treatment introduces shallower electron traps, and the special electrostatic potential after fluorination can significantly suppress the space charge accumulation at the interface in the HVDC cable accessory.

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