Metal−polymer interface plays a crucial role in controlling the dielectric performance in all flexible electronics. Ideally, the formation of the Schottky barrier due to the large band offset of the electron affinity of the polymer over the work function of the electrode should sufficiently impede the charge injection. Arguably, however, such an injection barrier has hardly been indisputably verified in polymer−metal junctions due to the everexisting surface states, which dramatically compromise the barrier thus leading to undesired high electrical conduction. Here, we demonstrate experimentally a clear negative correlation between the breakdown strength and the density of surface states in polymer dielectrics. The existence of surface states reduces the effective barrier height for charge injection, as further revealed by density functional theory calculations and photoinjection current measurements. Based on these findings, we present a surface engineering method to enhance the breakdown strength with the application of nanocoatings on polymer films to eliminate surface states. The density of surface states is reduced by 2 orders of magnitude when the polymer is coated with a layer of two-dimensional hexagonal boron nitride nanosheets, leading to about 100% enhancement of breakdown strength. This work reveals the critical role played by surface states on electrical breakdown and provides a versatile surface engineering strategy to curtail surface states, broadly applicable for all polymer dielectrics.
Polymer dielectrics are essential for advanced electrical and electronic power systems due to their ultrafast charge–discharge rate. However, a long‐standing challenge is to maintain their dielectric performance at high temperatures. Here, a layered barium titanate/polyamideimide nanocomposite reinforced with rationally designed interfaces is reported for high‐temperature high‐energy‐density dielectrics. Nanocoatings composed of 2D montmorillonite nanosheets with anisotropic conductivities are interposed at two kinds of macroscopic interfaces: 1) the interfaces between adjacent layers in the nanocomposites (inside) and 2) the interfaces between the surface of the nanocomposite and the electrode (outside). By revealing the charge transport behavior with Kelvin probe force microscope, surface potential decay, and finite element simulation, it is demonstrated that the outside nanocoatings are observed to diminish charge injection from the electrode, while the inside nanocoatings can suppress the kinetic energy of hot carriers by redirecting their transport. In this interface‐reinforced nanocomposite, an ultrahigh energy density of 2.48 J cm−3, as well as a remarkable charge–discharge efficiency >80%, is achieved at 200 °C, six times higher than that of the nanocomposite without interfacial nanocoatings. This research unveils a novel approach for the structural design of polymer nanocomposites based on engineered interfaces to achieve high‐efficient and high‐temperature capacitive energy storage.
Low-voltage circuit breakers provide essential protection for industrial and residential power installations, by taking advantage of the voltage drop at the electrode–plasma interface to force current zero. This is accomplished by using the magnetic force and unbalanced pressure on the arc as the contacts open to push the arc toward a stack of steel plates that break the arc into subarcs and thereby multiply the number of voltage drops. As the fault current can be high, substantial energy can be dissipated, which results in interactions among the arc and solid counterparts in terms of wall ablation and metal evaporation. In this study, ablation experiments are conducted to demonstrate its great influence on the arc voltage and on the pressure field. Significant progress has been accomplished in the computation of arc dynamics through the coupling of fluid motion with electromagnetics, although an important mechanism in arc breaking simulation, the effect of Stefan flow caused by species generation, has not been considered. We report out a numerical approach for taking into account the effect of Stefan flow, particularly for the breakers with high gasifying wall materials. This approach accounts for the diffusion induced convection due to added-in species from the evaporation surfaces, which will largely influence the flow field and the properties of the plasma mixture. Apart from the voltage drop, this mechanism plays an important role in simulating arc interruption. The ability of conducting Stefan flow computation further enhances the understanding of arc behaviors and improves the design of practically oriented low-voltage circuit breakers.
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