MOF 235 was fabricated by a facile microwave-assisted method. It showed excellent visible-light photocatalytic activity in the presence of H2O2. It displays a high chemical stability for repeated RhB degradation reactions.

Carboxymethyl cellulose, a hydrophobic derivative from cellulose that can be prepared from different biomass, has been widely applied in food, medicine, chemical, and other industries. In this work, carboxymethyl cellulose was used as the additive to improve the hydrophobicity and strength of carboxylated starch film, which is prepared from starch catalyzed by bio-α-amylase. This study investigated the effects of different bio-α-amylase dosages (starch 0.5%, starch 1%) and different activation times (10, 30 min) on starch to prepare the carboxylated starch. The effects of different carboxymethyl cellulose content on the carboxylated starch film were investigated by analysis viscosity, fourier-transform infrared spectroscopy, thermogravimetric analysis, differential scanning calorimetry, x-ray powder diffraction, scanning electron microscope, and contact angle. The results showed that preparing carboxylated starch using activated starch increased the carboxyl content, which could improve the effectiveness of the activated enzyme compared to prolonging the activation time. The carboxyl starch prepared by enzyme catalysis had a lower gelatinization temperature, and enzyme activation destroyed the crystallization area of the starch, thus facilitating the carboxylation reaction. The addition of 15% carboxymethyl cellulose improved the mechanical properties of the prepared film with maximum tensile strength of 44.8 MPa. Carboxymethyl cellulose effectively improved the hydrophobicity of the starch film with the addition amount of 10–30%, while hydrophobic property was stable at 66.8° when the addition amount was exceeded to 35%. In this work, it can be found that carboxymethyl cellulose improve the mechanical and hydrophobic properties of starch film, laying the foundation for the application of carboxylated starch materials.

Surplus lignin, which is inefficiently used, is generated in the forestry industry. Currently, most studies use lignin instead of phenol to synthesize thermosetting resins which cannot be reprocessed, thus affecting its application field. Thermoplastic phenolic resin has an orderly structure and excellent molding performance, which can greatly improve its application field and economic value. Herein, phenol was partially replaced with enzymolysis lignin (without treatment), generating lignin-based high-ortho thermoplastic phenolic resins (LPRs), and then lignin-based phenolic fibers (LPFs) were prepared by melt spinning. FTIR, 13C-NMR and GPC were used to characterize the ortho–para position ratio (O/P value), molecular weight and its distribution (PDI), and rheological properties of the resin. TG, XRD, SEM and tensile property studies were used to determine the thermal stability, orientation, and surface morphology of the fiber. Lignin addition resulted in the decline of the O/P value and molecular weight of the resin. For the 10% LPR, the O/P value, Mw, and PDI were 1.28, 4263, and 2.74, respectively, with the fiber exhibiting relatively good spinnability. The tensile strength and elongation at break of the 10% LPF were 160.9 MPa and 1.9%, respectively. The addition of lignin effectively improved the thermal properties of the fiber, and the carbon yields of 20% LPF before and after curing were 39.7% and 53.6%, respectively, which were 22.2% and 13.7% higher than that of the unmodified fiber, respectively.

Lignin has many potential applications and is a biopolymer with a three-dimensional network structure. It is composed of three phenylpropane units, p-hydroxyphenyl, guaiacyl, and syringyl, connected by ether bonds and carbon–carbon bonds, and it contains a large number of phenol or aldehyde structural units, resulting in complex lignin structures. This limits the application of lignin. To expand the application range of lignin, we prepared lignin thermoplastic phenolic resins (LPRs) by using lignin instead of phenol; these LPRs had molecular weights of up to 1917 g/mol, a molecular weight distribution of 1.451, and an O/P value of up to 2.73. Due to the complex structure of the lignin, the synthetic lignin thermoplastic phenolic resins were not very tough, which greatly affected the performance of the material. If the lignin phenolic resins were toughened, their application range would be substantially expanded. Polybutylene succinate (PBS) has excellent processability and excellent mechanical properties. The toughening effects of different PBS contents in the LPRs were investigated. PBS was found to be compatible with the LPRs, and the flexible chain segments of the small PBS molecules were embedded in the molecular chain segments of the LPRs, thus reducing the crystallinities of the LPRs. The good compatibility between the two materials promoted hydrogen bond formation between the PBS and LPRs. Rheological data showed good interfacial bonding between the materials, and the modulus of the high-melting PBS made the LPRs more damage resistant. When PBS was added at 30%, the tensile strength of the LPRs was increased by 2.8 times to 1.65 MPa, and the elongation at break increased by 31 times to 93%. This work demonstrates the potential of lignin thermoplastic phenolic resins for industrial applications and provides novel concepts for toughening biobased aromatic resins with PBS.

LPFBs are mainly applied in the lower party of glass furnace regenerator as checker works or walls. They are subjected to the loads of upper refractory materials at high temperature. So the creep behavior of them should be considered to predict the longevity of the regenerator. Two kinds of LPFBs were chosen as the test samples. It is shown that the creep rates of them under different stresses (0.1MPa, 0.2MPa, and 0.3MPa) and different temperatures (1200°C and 1280°C) are within 0.2%. LPFB1 with lower apparent porosity is more sensitive to temperature. LPFB2 is more sensitive to stress. The relationship between the creep and other mechanical properties is: the higher the Al2O3 content, the higher the bulk density, the lower the apparent porosity, and the higher the refractoriness under load of LPFB, the lower the total strain range of it. A model combined with phase diagram was built to analyze the microstructures and the creep curves with different shapes of the two LPFBs.

Cement addition, water addition and wet curing period are selected as the effects on cold modulus of rupture and cold crushing strength of one LCRC. According to the molding morphologies of the castables, when the water addition is 8 wt. %, the castable is suitable to be cast by vibration fashion, and the high strength of the castable can be kept because the hardening time is not very long. Through an orthogonal experiment, it is shown that cold modulus of rupture and cold crushing strength increase with increasing cement addition, decrease with increasing water addition, almost do not affect by the wet curing period. It is recommended that 4 wt. % cement addition and 8 wt. % water addition of the castable are used when it is applied to industries.