Many materials in nature change colours in response to stimuli, making them attractive for use as sensor platform. However, both natural materials and their synthetic analogues lack selectivity towards specific chemicals, and introducing such selectivity remains a challenge. Here we report the self-assembly of genetically engineered viruses (M13 phage) into targetspecific, colourimetric biosensors. The sensors are composed of phage-bundle nanostructures and exhibit viewing-angle independent colour, similar to collagen structures in turkey skin. On exposure to various volatile organic chemicals, the structures rapidly swell and undergo distinct colour changes. Furthermore, sensors composed of phage displaying trinitrotoluene (TNT)-binding peptide motifs identified from a phage display selectively distinguish TNT down to 300 p.p.b. over similarly structured chemicals. Our tunable, colourimetric sensors can be useful for the detection of a variety of harmful toxicants and pathogens to protect human health and national security.
As practical interest in flexible/or wearable power-conversion devices increases, the demand for high-performance alternatives to thermoelectric (TE) generators based on brittle inorganic materials is growing. Herein, we propose a flexible and ultralight TE generator (TEG) based on carbon nanotube yarn (CNTY) with excellent TE performance. The as-prepared CNTY shows a superior electrical conductivity of 3147 S/cm due to increased longitudinal carrier mobility derived from a highly aligned structure. Our TEG is innovative in that the CNTY acts as multifunctions in the same device. The CNTY is alternatively doped into n- and p-types using polyethylenimine and FeCl, respectively. The highly conductive CNTY between the doped regions is used as electrodes to minimize the circuit resistance, thereby forming an all-carbon TEG without additional metal deposition. A flexible TEG based on 60 pairs of n- and p-doped CNTY shows the maximum power density of 10.85 and 697 μW/g at temperature differences of 5 and 40 K, respectively, which are the highest values among reported TEGs based on flexible materials. We believe that the strategy proposed here to improve the power density of flexible TEG by introducing highly aligned CNTY and designing a device without metal electrodes shows great potential for the flexible/or wearable power-conversion devices.
Bioinspired piezoelectric nanogenerators based on phage nanopillars are inceptively demonstrated, and the electrical power from phage nanopillars holds promise for the development of implantable and wearable electronics.
Sub-10 nm patterns prepared by directed self-assembly (DSA) of block copolymer (BCP) thin films offer a breakthrough method to overcome the limitations of photolithography. Perpendicular orientation of the BCP nanostructures is essential for lithographic applications, but dissimilar surface/interfacial energies of two blocks generally favour parallel orientations, so that the perpendicular orientation could only be obtained under very limited conditions. Here, we introduce a generalized method for creating perpendicular orientations by filtered plasma treatment of the BCP films. By cross-linking the surface of disordered BCP films using only physical collisions of neutral species without ion bombardment or UV irradiation, neutral layers consistent with the BCP volume fraction are produced that promote the perpendicular orientations. This method works with BCPs of various types, volume fractions, and molecular weights individually at the top and bottom interfaces, so it was applied to orientation-controlled 3D multilayer structures and DSA processes for sub-10 nm line-spacing patterns.
Using simple microwave irradiation under the presence of sodium amide as a nitrogen source, preparation of nitrogen-doped graphene nanosheets has been successfully demonstrated. It is notable that exfoliation and nitrogen doping of graphite to nitrogen-doped graphene simultaneously occurred during the microwave irradiation within a minute, and nitrogen content of the doped graphene could reach up to 8.1%. It was also found that the binding configuration of nitrogen atom on graphitic layer consisted of various nitrogen-containing moieties such as pyridine-N, pyrrolic-N, and quaternary-N, and their composition was changed as a function of irradiation power. Although formation of undoped reduced graphene oxide by microwave irradiation resulted in slight increase of electrical conductivity because of the reductive recovery of oxidized graphite to graphene, nitrogen doping involved during irradiation induced much more notable increase of electrical conductivity more than 300 S cm(-1). Furthermore, nitrogen-doped graphene showed highly enhanced capacitive performance than that of undoped reduced graphene oxide, the specific capacitance of 200 F/g (current density of 0.5 A/g), which ascribes the pseudocapacitive effect from the incorporation of nitrogen atom on graphitic layer.
As practical interest in stretchable electronics increases for future applications in wearables, healthcare, and robotics, the demand for electrical interconnects with high electrical conductivity, durability, printability, and adhesion is growing. Despite the high electrical conductivity and stretchability of most previous interconnects, they lack stable conductivity against strain and adhesion to stretchable substrates, leading to a limitation for their practical applications. Herein, we propose a stretchable conductive adhesive consisting of silver particles with carbon nanotube as an auxiliary filler in silicone adhesives. The conductive adhesive exhibits a high initial conductivity of 6450 S cm–1. They show little change in conductivity over 3000 stretching cycles at 50% strain, currently the highest stability reported for elastic conductors. Based on strong adhesion to stretchable substrates, the gel-free, dry adhesives printed on an elastic bandage for electrocardiography monitoring exhibit an extremely stable performance upon movement of the subject, even after several cycles of detachment–reattachment and machine washing.
Stretchable energy storage devices are of great interest because of their potential applications in body-friendly, skin-like, wearable devices. However, stretchable batteries are very challenging to fabricate. The electrodes must have a degree of stretchability because the active materials occupy most of the volume, and the separator and packaging should also be stretchable. Here, an all-component stretchable lithium-ion battery was realized by leveraging the structural stretchability of re-entrant micro-honeycomb graphene−carbon nanotube (CNT)/active material composite electrodes and a physically cross-linked gel electrolyte, without using an inactive elastomeric substrate or matrix. Active materials interconnected via the entangled CNT and graphene sheets provided a mechanically stable porous network framework, and the inwardly protruding framework in the re-entrant honeycomb structure allowed for structural stretching during deformation. The composite network consisting solely of binder-free, highly conductive materials provided superior electron transfer, and vertically aligned microchannels enabled facile ion transport. Additionally, the physically cross-linked gel electrolyte increased the mechanical stability upon deformation of the electrodes and was effective as a stretchable separator. The resulting stretchable battery showed a high areal capacity of 5.05 mAh•cm −2 , superior electrochemical performance up to 50% strain under repeated (up to 500) stretch−release cycles, and long-term stability of 95.7% after 100 cycles in air conditions.
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