Transition metal dichalcogenides (TMDs), transition metal carbides (TMCs), and transition metal oxides (TMOs) have been widely investigated for electrocatalytic applications owing to their abundant active sites, high stability, good conductivity, and various other fascinating properties. Therefore, the synthesis of composites of TMDs, TMCs, and TMOs is a new avenue for the preparation of efficient electrocatalysts. Herein, we propose a novel low-cost and facile method to prepare TMD–TMC–TMO nano-hollow spheres (WS2–WC–WO3 NH) as an efficient catalyst for the hydrogen evolution reaction (HER). The crystallinity, morphology, chemical bonding, and composition of the composite material were comprehensively investigated using X-ray diffraction, Raman spectroscopy, field emission scanning electron microscopy, and X-ray photoelectron spectroscopy. The results confirmed the successful synthesis of the WS2–WC–WO3 NH spheres. Interestingly, the presence of nitrogen significantly enhanced the electrical conductivity of the hybrid material, facilitating electron transfer during the catalytic process. As a result, the WS2–WC–WO3 NH hybrid exhibited better HER performance than the pure WS2 nanoflowers, which can be attributed to the synergistic effect of the W–S, W–C, and W–O bonding in the composite. Remarkably, the Tafel slope of the WS2–WC–WO3 NH spheres was 59 mV dec−1, which is significantly lower than that of the pure WS2 NFs (82 mV dec−1). The results also confirmed the unprecedented stability and superior electrocatalytic performance of the WS2–WC–WO3 NH spheres toward the HER, which opens new avenues for the preparation of low-cost and highly effective materials for energy conversion and storage applications.
The electrochemical reduction of CO2 to diverse value‐added chemicals is a unique, environmentally friendly approach for curbing greenhouse gas emissions while addressing sluggish catalytic activity and low Faradaic efficiency (FE) of electrocatalysts. Here, zeolite‐imidazolate‐frameworks‐8 (ZIF‐8) containing various transition metal ions—Ni, Fe, and Cu—at varying concentrations upon doping are fabricated for the electrocatalytic CO2 reduction reaction (CO2RR) to carbon monoxide (CO) without further processing. Atom coordination environments and theoretical electrocatalytic performance are scrutinized via X‐ray absorption spectroscopy (XAS) and density functional theory (DFT) calculations. Upon optimized Cu doping on ZIF‐8, Cu0.5Zn0.5/ZIF‐8 achieves a high partial current density of 11.57 mA cm–2 and maximum FE for CO of 88.5% at –1.0 V (versus RHE) with a stable catalytic activity over 6 h. Furthermore, the electron‐rich sp2 C atom facilitates COOH* promotion after Cu doping of ZIF‐8, leading to a local effect between the zinc–nitrogen (Zn–N4) and copper–nitrogen (Cu–N4) moieties. Additionally, the advanced CO2RR pathway is illustrated from various perspectives, including the pre‐H‐covered state under the CO2RR. The findings expand the pool of efficient metal–organic framework (MOF)‐based CO2RR catalysts, deeming them viable alternatives to conventional catalysts.
Metal-organic frameworks (MOFs) constitute a class of crystalline porous materials employed in storage and energy conversion applications. MOFs possess characteristics that render them ideal in the preparation of electrocatalysts, and exhibit excellent performance for the hydrogen evolution reaction (HER). Herein, H–Ni/NiO/C catalysts were synthesized from a Ni-based MOF hollow structure via a two-step process involving carbonization and oxidation. Interestingly, the performance of the H–Ni/NiO/C catalyst was superior to those of H–Ni/C, H–NiO/C, and NH–Ni/NiO/C catalysts for the HER. Notably, H–Ni/NiO/C exhibited the best electrocatalytic activity for the HER, with a low overpotential of 87 mV for 10 mA cm−2 and a Tafel slope of 91.7 mV dec−1. The high performance is ascribed to the synergistic effect of the metal/metal oxide and hollow architecture, which is favorable for breaking the H–OH bond, forming hydrogen atoms, and enabling charge transport. These results indicate that the employed approach is promising for fabricating cost-effective catalysts for hydrogen production in alkaline media.
Summary In this study, different morphologies of molybdenum disulfide (MoS2), including MoS2 nanoparticle (NP), MoS2 nanoflower (NF), MoS2 nanosphere (NS), MoS2 nanohollow (NH), and MoS2/MoO2 composite, are successfully synthesized via a facile‐route hydrothermal process employing different solutions. The structure and chemical bonding of the different morphologies of MoS2 are investigated via X‐ray diffraction (XRD), Raman spectroscopy, scanning electron microscopy (SEM), and X‐ray photoelectron spectroscopy (XPS). Thereafter, the synthesized materials are applied to the hydrogen evolution reaction (HER) employing a three‐electrode system in a standard acidic medium (0.5 M H2SO4). The MoS2 NH exhibits higher performance: an overpotential of −230 mV at −10 mAcm−2, a Tafel slope of 64 mVdec−1, a high double‐layer capacitance (Cdl) of 11.98 mFcm−2 and larger BET surface area (22.59 m2/g), as well as super stability after stability tests, representing the best catalytic behavior among the synthesized materials. The results indicate that the electrocatalytic efficiencies of materials depend on their morphologies which is highly related to the surface area of catalysts. The results avail a novel avenue for synthesizing the various morphologies of MoS2, as well as the new morphology of MoS2 (MoS2 NH). It can be a promising material for electrocatalytic and energy‐storage applications.
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