Single-photon emitters play an essential role in quantum technologies, including quantum computing and quantum communications. Atomic defects in hexagonal boron nitride ( h-BN) have recently emerged as new room-temperature single-photon emitters in solid-state systems, but the development of scalable and tunable h-BN single-photon emitters requires external methods that can control the emission energy of individual defects. Here, by fabricating van der Waals heterostructures of h-BN and graphene, we demonstrate the electrical control of single-photon emission from atomic defects in h-BN via the Stark effect. By applying an out-of-plane electric field through graphene gates, we observed Stark shifts as large as 5.4 nm per GV/m. The Stark shift generated upon a vertical electric field suggests the existence of out-of-plane dipole moments associated with atomic defect emitters, which is supported by first-principles theoretical calculations. Furthermore, we found field-induced discrete modification and stabilization of emission intensity, which were reversibly controllable with an external electric field.
In a quantum network involving multiple communicating parties, an important goal is to establish high-quality pairwise entanglement among the users without introducing multiple entangled-photon sources which would necessarily complicate the overall network setup. Moreover, it is preferable that the pairwise entanglement of photons is in the time-bin degree of freedom as the photonic time-bin qubit is ideally suited for fiber-optic distribution. Here, we report an experimental demonstration of a field-deployable quantum communication network involving multiple users, all of whom share pairwise entanglement in the time-bin degree of freedom of photons. In particular, by utilizing a single spontaneous-parametric down-conversion source which produces a broadband pair of photons and the wavelength-division demultiplexing/multiplexing technology, all the communicating parties within the network are always simultaneously ready for quantum communication. To further demonstrate the practical feasibility of a quantum network with time-bin entanglement over a wavelength-multiplexed fiber network, we demonstrate entangled-photon quantum key distribution with three users, each separated by 60 km of optical fibers.
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