Gas chromatograms of saturated hydrocarbons of shale rock extracts show three patterns of n-alkanets in the second member of Funning formation (E1f2) in Jinhu Sag of Subei basin, eastern China. Three patterns of n-alkanets are the odd-to-even carbon predominance, the even-to-odd carbon predominance, and the even and odd carbon predominance coexisting, respectively. In this paper, the characteristics of n-alkanet coexisting even and odd carbon predominance and its origin and sedimentary environment are investigated only. The short-chain n-alkanets and long-chain n-alkanets are characterized by pronounced odd carbon predominance, with the dominant carbon of nC15, nC17 and of nC25, nC27, nC29 and nC31. The mid-chain n-alkanets are dominated by even carbon predominance, with the dominant carbon of nC20 and nC22. The composition of biomarkers are characterized by phytane preference, high gamma cerate abundance, the presence of β-carotene and C24-tetracyclic terrapin, which indicate that the organic matter in source rocks deposited in an anoxic, hyper saline lacus trine environment. The biomarkers are no homogeneous, which shows that salinity and redo is not constant in pale-lacus trine. The n-alkanets are mainly derived from algae in the ancient lake and macro pyres on land or around the edges of the ancient lake. The n-alkanets distribution patterns of the dark shales studied are believed not to be dependent on the redo in the depositional environments or the salinity of the water body, but to be associated with original organic matter composition.
The Lower Silurian marine shale is widely distributed in Northwestern Hunan and features in a large thickness of dark shale showed at outcrops. However, the accumulation conditions and gas content is unknown. The sedimentary facies, thickness and distribution, organic matter types and content, maturity, reservoir properties and gas content of the Lower Silurian black shale in Northwestern Hunan were investigated by field observation, sampling and experimental analysis. The results show that the black shales sedimentary environment is deep water continental shelf, with featured in abundant fossil. The burial depth of the Lower Silurian black shale is 0-3000 m, and its thickness is 10-40m while the average TOC is 1.0% and average Ro is 2.9%. For the disadvantaged sedimentary facies and shallow depth, the maximum gas content of the Lower Silurian black shale from well site desorption test is 0.59m3/t only, but the result of isothermal adsorption simulate test show that the Lower Silurian black shale have a good adsorption capacity, and can generate a large number of shale gas in Northwestern Hunan where better deposition conditions and suitable depth exist in.
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