Recent theoretical advances in simulating the structural evolution of metal/alloy nanoparticles under working conditions are reviewed, coupled with the qualitative comparison to the experiments and a brief introduction of MOSP software.

Urban soils can contribute to organic carbon sequestration. The socioeconomic drivers of soil organic carbon (SOC) in urban areas may differ between regions due to the different land tenure and its derived green space management regimes. Currently, few studies focus on regions where public ownership of land was implemented. We examined the SOC storage and driving factors of urban green spaces in Guangzhou, China at 0–20 cm depth by variance and regression analysis. Our results showed that the total SOC storage did not vary significantly among green space types, with an average value of 2.59 ± 1.31 kg/m2. SOC increased with plot age (2–87 years) by 0.025 kg/m2/year (p = 0.026) and plot size (63–2058 m2) by 0.001 kg/m2/m2 (p = 0.026). Disturbance intensity was negatively correlated to SOC storage. Green space maintenance practices could promote SOC sequestration, but this benefit may be offset by high-intensity disturbances such as trampling, litter and debris removal and fragmentation of green spaces. To increase urban residential SOC storage, except for remediation of compacted soils, it is essential to promote house owners’ initiative in green space management and conservation by improving the current residential green space management regimes.

Empirical evidence shows that the expansion of impervious surface threatens soil organic carbon (SOC) sequestration in urbanized areas. However, the understanding of deep soil excavation due to the vertical expansion of impervious surface remains limited. According to the average soil excavation depth, we divided impervious surface into pavement (IS20), low-rise building (IS100) and high-rise building (IS300). Based on remote-sensing images and published SOC density data, we estimated the SOC storage and its response to the impervious surface expansion in the 0–300 cm soil depth in Guangzhou city, China. The results showed that the total SOC storage of the study area was 8.31 Tg, of which the top 100 cm layer contributed 44%. The impervious surface expansion to date (539.87 km2) resulted in 4.16 Tg SOC loss, of which the IS20, IS100 and IS300 contributed 26%, 58% and 16%, respectively. The excavation-induced SOC loss (kg/m2) of IS300 was 1.8 times that of IS100. However, at the residential scale, renovating an IS100 plot into an IS300 plot can substantially reduce SOC loss compared with farmland urbanization. The gains of organic carbon accumulation in more greenspace coverage may be offset by the loss in deep soil excavation for the construction of underground parking lots, suggesting a need to control the exploitation intensity of underground space and promote residential greening.