Flexible and wearable electronic devices with excellent performance have been desired for making the next generation of electronic products. Herein, the synthesis of CuCoS nanosheets on flexible carbon fiber textile (CFT) by a facile one-step and scalable hydrothermal procedure is reported, which is free from the sulphurization process used in the conventional synthesis of mixed metal sulphospinels. The as-prepared CuCoS nanostructures on CFT can provide rich reaction sites and short ion diffusion paths. The CuCoS nanosheets are employed as the free-standing electrodes for two different applications: high-performance supercapacitors and non-enzymatic glucose sensors. When employed as a flexible electrode material for supercapacitors, the electrode presents ultrahigh performance in energy storage with a specific capacitance of 3321.6 F g at 5 A g, which is attributed to the suitable mass loading and special morphology of the as-prepared nanosheets. Remarkably, a specific capacitance of 2931.4 F g is still retained at the high current density of 30 A g, suggesting its excellent rate capability. The specific capacitance retains 87.1% after 3000 cycles, reflecting excellent cycling performance. For real applications, a flexible symmetric supercapacitor is assembled based on CuCoS nanosheets, which achieves a high energy density of 64.6 W h kg at 499.7 W kg and a maximum power density of 2081.5 W kg at 45.1 W h kg. Besides serving as a free-standing electrode for non-enzymatic glucose sensors, CuCoS nanosheets have remarkable electrocatalytic activity towards glucose oxidation with a high sensitivity of 3852.7 μA mM cm and an extraordinary linear range up to 3.67 mM. The experimental results suggest that CuCoS nanosheets are more suitable for non-enzymatic glucose sensors than the related single/binary transition metal oxides/sulfides. Such a superior performance demonstrates that CuCoS nanosheets hold great potential for use as flexible multifunctional electronic devices including supercapacitors and non-enzymatic glucose sensors.
Wireless electric energy transmission is an important energy supply technology. However, most wireless energy supply based on electromagnetic induction cannot be used for energy transmission through a metal chamber. Herein, a novel idea for wireless electric energy transmission through various isolated solid media based on triboelectric nanogenerator (TENG) is presented. The electric energy is first transformed into mechanical vibration energy in mechanical wave that can propagate well in solid medium, and then the vibration energy is harvested by a TENG. By employing the spring steel sheets and freestanding triboelectric‐layer structure, the vibration TENG as an energy conversion unit has the advantages of high efficiency and facilitation, boosting this wireless energy transmission technology to be an alternative way of delivering electric energy through metal medium. The working principle and output performance have been systematically studied. A commercial capacitor can be charged from 0 to 10 V in 33 and 86 s isolated by an acrylic plate and a copper plate in thickness of 3 mm, respectively. The wireless electric transmission technology is also applied to deliver electric energy into a vacuum glove box and across glass wall successfully. This novel technology has great potential applications in implantable microelectronic devices, encrypted wireless communication, and even nondestructive testing.
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