Metal selenides have caused widespread concern due to their high theoretical capacities and appropriate working potential; however, they suffer from large volume variation during cycling and low electrical conductivity, which limit their practical applications. In this article, a three-dimensional (3D) porous carbon framework embedded with homogeneous FeSe 2 nanoparticles (3D porous FeSe 2 /C composite) was synthesized by a facile calcined approach, following a selenized method without a template. As the uniformity of FeSe 2 nanoparticles and 3D porous structure are beneficial to accommodate volume stress upon cycling and shorten electrons/ions transport path, associated with carbon as a buffer matrix for increasing conductivity, the 3D porous FeSe 2 /C composite displays excellent electrochemical properties with high reversible capacities of 798.4 and 455.0 mA h g −1 for lithium-ion batteries and sodium-ion batteries, respectively, when the current density is 100 mA g −1 after 100 cycles. In addition, the as-prepared composite exhibits good cycling stability as compared to bare FeSe 2 nanoparticles. Therefore, the facile synthetic strategy in the current work provides a new perspective in constructing a high-performance anode.
Ferromagnetic resonance (FMR) is one of the most important characteristics of soft magnetic materials, which practically sets the maximum operation speed of these materials. There are two FMR modes in exchange coupled ferromagnet/nonmagnet/ferromagnet sandwich films. The acoustic mode has relatively lower frequency and is widely used in radio‐frequency/microwave devices, while the optical mode is largely neglected due to its tiny permeability even though it supports much higher frequency. Here, a realistic method is reported to enhance the permeability in the optical mode to an applicable level. FeCoB/Ru/FeCoB trilayers are carefully engineered with both uniaxial magnetic anisotropy and antiferromagnetic interlayer exchange coupling. This special magnetic structure exhibits a high optical mode frequency up to 11.28 GHz and a maximum permeability of 200 at resonance. An abnormally low inverse switch field (<200 Oe, less than 1/5 of the single layer) is observed which can effectively switch the system from optical mode with higher frequency into acoustic mode with lower frequency. The optical mode frequency and inverse switch field can be controlled by tailoring the interlayer coupling strengths and the uniaxial anisotropy fields, respectively. The tunable optical mode resonance thus can increase operation frequency while reduce operation field overhead in FMR based devices.
Polyoxometalate (POM) as an "electronic sponge" can store a great number of electrons; however, shortcomings of poor conductivity and solubility in electrolytes cause a significant decrease in specific capacity and poor rate capability. To address the aforementioned disadvantages, a dual strategy was proposed, including coating the conductive polypyrrole (PPy) and utilizing nitrogenous ligands (1,10-phenanthroline monohydrate = 1,10-phen) for metal−organic frameworks (MOFs) to fabricate a [Cu(1,10-phen)(H 2 O) 2 ] 2 [Mo 6 O 20 ]@PPy (Cu-POMOF@PPy) composite, effectively confining the POM in MOFs to avoid dissolution of POM in the electrolyte and improve electrochemical stability. Simultaneously, the PPy shell could improve the conductivity, contribute extra capacity, and alleviate volume variation of Cu-POMOF during cycling. Therefore, the final Cu-POMOF@PPy composite provides an excellent specific capacity of around 769 mA h g −1 at 0.1 A g −1 after 160 cycles and good rate performance, associated with great cycling stability (319 mA h g −1 at 2 A g −1 after 500 cycles). Moreover, the electrochemical reaction mechanism of Cu-POMOF@PPy was investigated by ex situ XPS measurements, indicating that storage of electrons results from the reduction/oxidation of Mo atoms (Mo 6+ ↔ Mo 4+ ) and Cu atoms (Cu 2+ ↔ Cu 0 ). As a consequence, this work not only proposes a novel method for preparing POM-based lithium-ion batteries but also expands the variety of anode materials.
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