No abstract

A series of rare earth Dy³⁺, Tb³⁺, Eu³⁺ singly doped Gd₂Te₄O₁₁ (GTO) tellurite phosphors with intrinsic polarity were prepared by hydrothermal method. The phase structure, morphology and thermal stability of the phosphors were characterized. Their luminescence properties were tested in detail. The results show all those phosphors were crystalized into single phase of digadolinium tellurite with short rod-like shape. The maximum size achieved microns in axial direction. The phosphors have good thermal stability. For the GTO:Dy³⁺, the fluorescence emission under UV excitation is mainly located in the yellow-green region. The optimal doping concentration corresponding to the strongest excitation and emission is 2.5%, and the CIE color coordinates are (0.39, 0.43). The fluorescence decay curves show that the lifetime of the GTO:Dy³⁺ on ⁴F_9/2 energy level decreases gradually with increasing doping concentration of Dy³⁺, which may be related to the cross relaxation (CR) between Dy³⁺ ions. For the GTO:Eu³⁺, the fluorescence emission under UV excitation is mainly located in the red and orange-red regions. The emission intensity was enhanced with increasing doping concentration of Eu³⁺. When the doping concentration is 10%, the CIE color coordinates are (0.62, 0.38), which located in the orange-red region with high color purity. The fluorescence lifetime of Eu³⁺ on ⁵D₀ energy level is hardly affected by the change of Eu³⁺ doping concentration. For the GTO:Tb³⁺, with increasing the Tb³⁺ concentration, the fluorescence emission under UV excitation changes from blue-violet region to yellow-green region, which can be ascribed to the influence of CR between Tb³⁺ ions. The fluorescence decay behavior revealed that the Tb³⁺ ions on ⁵D₄ excited state may undergo energy transfer and reabsorption, which deviated fluorescence decay from the single exponential model. When the concentration of Tb³⁺ is 0.5%, the sample exhibits white light emission, having the CIE color coordinates of (0.33, 0.35) and color rendering index of 86. The measurements of temperature-dependent emission spectra show that the above-mentioned phosphors have good luminescent thermal stability. The internal quantum efficiencies (IQE) of those three types of phosphors were tested, and the IQE of GTO:Eu³⁺ are better than those of GTO:Dy³⁺ and GTO:Tb³⁺. All those phosphors still have much room for improvement in the luminescent performance. These phosphors have potential for the use of UV-excited white LED.