Potassium-ion
batteries (PIBs) are attracting intensive interest
for large-scale applications due to the high natural abundance of
potassium sources. However, the large radius of K+ makes
it difficult for electrode materials to accommodate the repeated K+ insertion and extraction. Thus, developing high-performance
electrode materials for PIBs remains a great challenge. Herein, we
present the rational design and fabrication of hierarchical carbon-coated
MoSe2/MXene hybrid nanosheets (MoSe2/MXene@C)
as a superior anode material for PIBs. Specifically, the highly conductive
MXene substrate can effectively relieve the aggregation of MoSe2 nanosheets and improve the electronic conductivity. Moreover,
the carbon layer enables us to reinforce the composite structure and
further enhance the overall conductivity of the hybrid nanosheets.
Meanwhile, strong chemical interactions are found at the interface
of MoSe2 nanosheets and MXene flakes, contributing to promoting
the charge-transfer kinetics and improving the structural durability.
Consequently, as an anode material for PIBs, the resulting MoSe2/MXene@C achieves a high reversible capacity of 355 mA h g–1 at 200 mA g–1 after 100 cycles
and an outstanding rate performance with 183 mA h g–1 at 10.0 A g–1. The presented design strategy holds
great promise for developing more-efficient electrode materials for
PIBs.
In this study, we present a novel application of thin magnesium fluoride films to form electron-selective contacts to n-type crystalline silicon (c-Si). This allows the demonstration of a 20.1%-efficient c-Si solar cell. The electron-selective contact is composed of deposited layers of amorphous silicon (∼6.5 nm), magnesium fluoride (∼1 nm), and aluminum (∼300 nm). X-ray photoelectron spectroscopy reveals a work function of 3.5 eV at the MgF2/Al interface, significantly lower than that of aluminum itself (∼4.2 eV), enabling an Ohmic contact between the aluminum electrode and n-type c-Si. The optimized contact structure exhibits a contact resistivity of ∼76 mΩ·cm(2), sufficiently low for a full-area contact to solar cells, together with a very low contact recombination current density of ∼10 fA/cm(2). We demonstrate that electrodes functionalized with thin magnesium fluoride films significantly improve the performance of silicon solar cells. The novel contacts can potentially be implemented also in organic optoelectronic devices, including photovoltaics, thin film transistors, or light emitting diodes.
A high Schottky barrier (> 0.65 eV) for electrons is typically found on lightly doped n-type crystalline (c-Si) wafers for a variety of contact metals. This behaviour is commonly attributed to the Fermi-level pinning effect and has hindered the development of n-type c-Si solar cells, whilst its p-type counterparts have been commercialised for several decades, typically utilising aluminium alloys in full-area, and more recently, partial-area rear contact configurations. Here we demonstrate a highly conductive and thermally stable electrode composed of a magnesium oxide / aluminium (MgO x /Al) contact, achieving moderately low resistivity Ohmic contacts on lightly doped n-type c-Si. The electrode, functionalized with nanoscale MgO x films, significantly enhances the performance of n-type c-Si solar cells to a power conversion efficiency of 20%, advancing n-type c-Si solar cells with full-area dopantfree rear contacts to a point of competitiveness with the standard p-type architecture. The low thermal budget of the cathode formation, its dopant-free nature, and the simplicity of the device structure enabled by the MgO x /Al contact open up new possibilities in designing and fabricating low-cost optoelectronic devices, including solar cells, thin film transistors or light emitting diodes.
Magnesium coated by different transition metals (TM: Ti, Nb, V, Co, Mo, or Ni) with a grain size in the nano-scale formed a core (Mg)–shell (TM) like structure which can catalyse dehydrogenation.
Controlling the concentration of charge carriers near the surface is essential for solar cells. It permits to form regions with selective conductivity for either electrons or holes and it also helps to reduce the rate at which they recombine. Chemical passivation of the surfaces is equally important, and it can be combined with population control to implement carrierselective, passivating contacts for solar cells. This paper discusses different approaches to suppress surface recombination and to manipulate the concentration of carriers by means of doping, work function and charge. It also describes some of the many surface-passivating contacts that are being developed for silicon solar cells, restricted to experiments performed by the authors.
Recent advances in the efficiency of crystalline silicon (c‐Si) solar cells have come through the implementation of passivated contacts that simultaneously reduce recombination and resistive losses within the contact structure. In this contribution, low resistivity passivated contacts are demonstrated based on reduced titania (TiOx) contacted with the low work function metal, calcium (Ca). By using Ca as the overlying metal in the contact structure we are able to achieve a reduction in the contact resistivity of TiOx passivated contacts of up to two orders of magnitude compared to previously reported data on Al/TiOx contacts, allowing for the application of the Ca/TiOx contact to n‐type c‐Si solar cells with partial rear contacts. Implementing this contact structure on the cell level results in a power conversion efficiency of 21.8% where the Ca/TiOx contact comprises only ≈6% of the rear surface of the solar cell, an increase of 1.5% absolute compared to a similar device fabricated without the TiOx interlayer.
We explore the performance of a statistical learning technique based on Gaussian Process (GP) regression as an efficient non-parametric method for constructing multi-dimensional potential energy surfaces (PES) for polyatomic molecules. Using an example of the molecule N 4 , we show that a realistic GP model of the six-dimensional PES can be constructed with only 240 potential energy points. We construct a series of the GP models and illustrate the convergence of the accuracy of the resulting surfaces as a function of the number of ab initio points. We show that the GP model based on ∼ 1500 potential energy points achieves the same level of accuracy as the conventional regression fits based on 16,421 points. The GP model of the PES requires no fitting of ab initio data with analytical functions and can be readily extended to surfaces of higher dimensions.
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