Renewable low-toxic gallic acid serves as an efficient organocatalyst in assistance of MnCO3 for aerobic oxidative coupling of thiols to symmetrical and/or unsymmetrical disulfanes in water.
To pursue a sustainable and efficient approach for aliphatic nitroester preparation from alcohol, Europium triflate-catalyzed nitration, that directly used commercial nitric acid, has been successfully developed. Gram scalability with operational...
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