The surface of Inconel 625, a nickel-base alloy, was strengthened by vacuum electron beam scanning technology. The evolution of its microstructure was analyzed by electron backscatter diffraction (EBSD) and the friction and wear tester (RETC). The results show that the FCC phase in the microstructure of Inconel 625 nickel-base alloy is stripped and islanded after electron beam scanning treatment. The austenite texture type changes and finally forms a typical cubic texture with a certain strength of S texture. With the increase in temperature of the focusing current, the wear resistance of nickel-base alloy plates first increases and then decreases. Under a 720 mA focusing current, the wear volume and wear rate are the lowest, which are 0.141525 mm3 and 1.41525 × 10−5 mm3/N∙m, respectively. The wear rate decreases by 26.64%, which may be related to the columnar crystals produced in the melting area. After electron beam surface modification, the oxidation wear and adhesive wear are relatively smaller than the original materials.

Inconel 625 nickel-base alloy was modified by electron beam surface alloying (EBSA) with TiC as the coating at different scanning speeds (80 mm/min, 100 mm/min, and 120 mm/min). Its microstructure evolution and friction and wear evolution were characterized using electron backscatter diffraction (EBSD), a microhardness tester, and a friction and wear tester (RTEC). The results indicated that the FCC phase in the microstructure of the Inconel 625 nickel-base alloy is island-shaped after EBSA. At different scanning speeds, the austenitic texture types will eventually form primarily S-texture accompanied by Goss texture and Brass texture of varying strengths. With an increase in scanning speed, the surface hardness of nickel-base alloys decreases. The highest surface hardness was 457 HB at 80 mm/min, and the surface hardness was 1.936 times higher than that of the base material. With an increase in scanning speed, the wear resistance of the nickel-base alloy plates decreased gradually. At the scanning speed of 80 mm/min, the wear volume and wear rate were the lowest, which were 0.9131 mm3 and 3.0437, respectively, and the wear rate decreased by 30.48%.

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