We have developed an efficient palladium-catalyzed denitrative N-arylation via cross-coupling of N–H heteroarenes with nitroarenes, one of the most inexpensive and fundamental feedstocks in the chemical industry. A variety of...
The transition-metal-catalyzed cross-coupling of aryl halides with silylation reagents is a powerful strategy for C(sp2)−Si bond formation. However, the need for the tedious preparation of aryl halides makes the reaction...
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