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Organic–inorganic hybrid material is a recent hot topic in the scientific community. The best band gap for the entire solar absorption spectrum is about 1.1 eV. However, the lead perovskite band gap is about 1.5 eV. Therefore, developing organic–inorganic hybrid material toward the broader light harvesting of the solar spectrum is extremely urgent. In this study, we prepare three kinds of organic–inorganic hybrid palladium perovskite materials, including (CH 3 NH 3 ) 2 PdCl 4 , (CH 3 NH 3 ) 2 PdCl 4– x Br x , and CH 3 NH 3 PdI 3 , for an optoelectronic response. The absorption cut offs of (CH 3 NH 3 ) 2 PdCl 4 , (CH 3 NH 3 ) 2 PdCl 4– x Br x , and CH 3 NH 3 PdI 3 are approximately 600, 700, and 1000 nm, respectively. The band gaps of (CH 3 NH 3 ) 2 PdCl 4 , (CH 3 NH 3 ) 2 PdCl 4– x Br x , and CH 3 NH 3 PdI 3 are determined to be approximately 2.15, 1.87, and 1.25 eV, respectively. To the best of our knowledge, this is the first study that discusses adsorption properties and photoelectric behavior of organic–inorganic hybrid palladium perovskite materials. Interestingly, the photoelectric response of the devices based on CH 3 NH 3 PdI 3 reaches 950 nm. The results will attract attention in the fields of optical recorders, optical memory, security, light capture, and light treatment.

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This article appeared in a journal published by Elsevier. The attached copy is furnished to the author for internal non-commercial research and education use, including for instruction at the authors institution and sharing with colleagues.Other uses, including reproduction and distribution, or selling or licensing copies, or posting to personal, institutional or third party websites are prohibited.

DEX therapy effectively suppresses AR symptoms, but does not result in the expected increase in the frequency of Tregs in vivo. Thus, whether GCs exert immunosuppressive effects by influencing the number of Tregs remains unresolved.