We report a new class of Zn anodes modified by a three-dimensional nanoporous ZnO architecture (Zn@ZnO-3D), which can accelerate the kinetics of Zn2+ transfer and deposition, inhibit dendrite growth, and reduce the side-reactions.
Zinc metal is considered as one of the best anode choices for rechargeable aqueous Zn-based batteries due to its high specific capacity, abundance, and safety. However, dendrite and corrosion issues remain a challenge for this system. Herein, sieve-element function (selective channel of Zn 2+ ) and uniform-pore distribution (≈3.0 nm) of a kaolin-coated Zn anode (KL-Zn) is proposed to alleviate these problems. Based on the artificial Zn metal/electrolyte interface, the KL-Zn anode not only ensures dendritefree deposition and long-time stability (800 h at 1.1 mA h cm −2 ), but also retards side reactions. As a consequence, KL-Zn/MnO 2 batteries can deliver high specific capacity and good capacity retention as well as a reasonably well-preserved morphology (KL-Zn) after 600 cycles at 0.5 A g −1 . This work provides a deep step toward high-performance rechargeable Zn-based battery system.
Zinc-ion batteries (ZIBs) is a promising electrical energy storage candidate due to its eco-friendliness, low cost, and intrinsic safety, but on the cathode the element dissolution and the formation of irreversible products, and on the anode the growth of dendrite as well as irreversible products hinder its practical application. Herein, we propose a new type of the inorganic highly concentrated colloidal electrolytes (HCCE) for ZIBs promoting simultaneous robust protection of both cathode/anode leading to an effective suppression of element dissolution, dendrite, and irreversible products growth. The new HCCE has high Zn2+ ion transference number (0.64) endowed by the limitation of SO42−, the competitive ion conductivity (1.1 × 10–2 S cm−1) and Zn2+ ion diffusion enabled by the uniform pore distribution (3.6 nm) and the limited free water. The Zn/HCCE/α-MnO2 cells exhibit high durability under both high and low current densities, which is almost 100% capacity retention at 200 mA g−1 after 400 cycles (290 mAh g−1) and 89% capacity retention under 500 mA g−1 after 1000 cycles (212 mAh g−1). Considering material sustainability and batteries’ high performances, the colloidal electrolyte may provide a feasible substitute beyond the liquid and all-solid-state electrolyte of ZIBs.
From 1997 to 2006, the Mars Global Surveyor (MGS) spacecraft provided magnetic field measurements while orbiting Mars, extensively sampling the magnetic field at an altitude of about 400 km (Acuña et al., 1998) after periapsis was raised upon completion of the aerobraking phase. The MGS mission discovered that Mars possesses many localized remanent magnetic fields, which most likely originate in the Martian lithosphere (Acuña et al., 1999). Remanent magnetic fields, otherwise known as crustal fields or lithospheric magnetic fields, are widely believed to be induced by an ancient core dynamo. Mars currently does not have a global dipole magnetic field as in the case of Earth and Mercury (Langlais et al., 2010). The most intense crustal fields of Mars are located in the Southern Hemisphere. These fields are 1 to 2 orders of magnitude stronger than the crustal fields on Earth (Kother et al., 2015;Voorhies et al., 2002), 3 to 4 orders of magnitude stronger than the crustal fields on Moon (Purucker & Nicholas, 2010) and Mercury (Johnson et al., 2015).
Using over 6 years of magnetic field data (October 2014–December 2020) collected by the Mars Atmosphere and Volatile EvolutioN, we conduct a statistical study on the three‐dimensional average magnetic field structure around Mars. We find that this magnetic field structure conforms to the pattern typical of an induced magnetosphere, that is, the interplanetary magnetic field (IMF) which is carried by the solar wind and which drapes, piles up, slips around the planet, and eventually forms a tail in the wake. The draped field lines from both hemispheres along the direction of the solar wind electric field (E) are directed toward the nightside magnetic equatorial plane, indicating that they are “sinking” toward the wake. These “sinking” field lines from the +E‐hemisphere (E pointing away from the plane) are more flared and dominant in the tail, while the field lines from the –E‐hemisphere (E pointing toward) are more stretched and “pinched” toward the plasma sheet. Such highly “pinched” field lines even form a loop over the pole of the –E‐hemisphere. The tail current sheet also shows an E‐asymmetry: the sheet is thicker with a stronger tailward trueJ→×trueB→ $\overrightarrow{J}\times \overrightarrow{B}$ force at +E‐flank, but much thinner and with a weaker trueJ→×trueB→ $\overrightarrow{J}\times \overrightarrow{B}$ (even turns sunward) at –E‐flank. Additionally, we find that IMF Bx can induce a kink‐like field structure at the boundary layer; the field strength is globally enhanced and the field lines flare less during high dynamic pressure.
Using the data sets of Mars Atmosphere and Volatile EvolutioN and OMNI for the period 2014 October 10–2020 February 14 and the heliocentric distance of 1–1.66 au, we investigate the statistical properties of solar wind upstream of Mars for the first time. The key parameters, including interplanetary magnetic field (IMF), proton density (N), bulk velocity (∣
V
∣), and dynamic pressure (P
dyn), are surveyed with regard to variations of solar activity level and heliocentric distance. We find that the parameters ∣IMF∣, N, and P
dyn monotonously decrease with heliocentric distance. Both ∣IMF∣ and P
dyn are generally stronger at a higher solar activity level (F
10.7 ≥ 70 sfu), while such activity has little relevance to N. In contrast, ∣
V
∣ basically keeps a median of about 370 km s−1 and is insensitive to the solar activity level and heliocentric distance. We also find that the IMF upstream of Mars at the higher solar activity level has a much smaller spiral angle in the inward sector; thus, IMF seems “straighter” than that in the outward sector, although that is not so for the inward sector of the upstream of Earth. Our statistical survey can be used as a reference for upstream solar wind of Mars at 1.4 ∼ 1.7 au, and could benefit the studies on solar wind as well as the Martian space environment.
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