Two-dimensional
transition-metal carbides/carbonitrides (MXenes)
with both superb electrical conductivity and hydrophilicity are promising
for fabricating multifunctional nanomaterials and nanocomposites.
However, the construction of three-dimensional (3D) and lightweight
MXene macroscopic assemblies with excellent electrical conductivity
and mechanical performances has not been realized due to the weak
gelation capability of MXene sheets. Herein, we demonstrate an efficient
approach for constructing highly conductive 3D Ti3C2T
x
porous architectures by graphene
oxide assisted hydrothermal assembly followed by directional freezing
and freeze-drying. The resultant hybrid aerogels exhibit aligned cellular
microstructure, in which the graphene sheets serve as the inner skeleton,
while the compactly attached Ti3C2T
x
sheets present as shells of the cell walls. The
porous and highly conductive architecture (up to 1085 S m–1) is highly efficient in endowing epoxy nanocomposite with a high
electrical conductivity of 695.9 S m–1 and an outstanding
electromagnetic interference (EMI)-shielding effectiveness of more
than 50 dB in the X-band at a low Ti3C2T
x
content of 0.74 vol %, which are the best
results for polymer nanocomposites with similar loadings of MXene
so far. The successful assembly methodology of 3D and porous architectures
of Ti3C2T
x
would
greatly widen the practical applications of MXenes in the fields of
EMI shielding, supercapacitors, and sensors.
We report a three-stage bench-scale column extraction process to selectively extract lithium chloride from geothermal brine. The goal of this research is to develop materials and processing technologies to improve the economics of lithium extraction and production from naturally occurring geothermal and other brines for energy storage applications. A novel sorbent, lithium aluminum layered double hydroxide chloride (LDH), is synthesized and characterized with X-ray powder diffraction, scanning electron microscopy, inductively coupled plasma optical emission spectrometry (ICP-OES), and thermogravimetric analysis. Each cycle of the column extraction process consists of three steps: (1) loading the sorbent with lithium chloride from brine; (2) intermediate washing to remove unwanted ions; (3) final washing for unloading the lithium chloride ions. Our experimental analysis of eluate vs feed concentrations of Li and competing ions demonstrates that our optimized sorbents can achieve a recovery efficiency of ∼91% and possess excellent Li apparent selectivity of 47.8 compared to Na ions and 212 compared to K ions, respectively in the brine. The present work demonstrates that LDH is an effective sorbent for selective extraction of lithium from brines, thus offering the possibility of effective application of lithium salts in lithium-ion batteries leading to a fundamental shift in the lithium supply chain.
Biofilm growth has been observed in Soviet/Russian (Salyuts and Mir), American (Skylab), and International (ISS) Space Stations, sometimes jeopardizing key equipment like spacesuits, water recycling units, radiators, and navigation windows. Biofilm formation also increases the risk of human illnesses and therefore needs to be well understood to enable safe, long-duration, human space missions. Here, the design of a NASA-supported biofilm in space project is reported. This new project aims to characterize biofilm inside the International Space Station in a controlled fashion, assessing changes in mass, thickness, and morphology. The space-based experiment also aims at elucidating the biomechanical and transcriptomic mechanisms involved in the formation of a “column-and-canopy” biofilm architecture that has previously been observed in space. To search for potential solutions, different materials and surface topologies will be used as the substrata for microbial growth. The adhesion of bacteria to surfaces and therefore the initial biofilm formation is strongly governed by topographical surface features of about the bacterial scale. Thus, using Direct Laser-Interference Patterning, some material coupons will have surface patterns with periodicities equal, above or below the size of bacteria. Additionally, a novel lubricant-impregnated surface will be assessed for potential Earth and spaceflight anti-biofilm applications. This paper describes the current experiment design including microbial strains and substrata materials and nanotopographies being considered, constraints and limitations that arise from performing experiments in space, and the next steps needed to mature the design to be spaceflight-ready.
Amphiphilic Janus MXene nanosheets are synthesized for the first time by a one-step transferring method, which can act as promising solid surfactants to stabilize emulsions, and assemble into macroscopic 2D ultrathin MXene films and 3D MXene aerogels.
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