Achieving high catalytic performance with the lowest possible amount of platinum is critical for fuel cell cost reduction. Here we describe a method of preparing highly active yet stable electrocatalysts containing ultralow-loading platinum content by using cobalt or bimetallic cobalt and zinc zeolitic imidazolate frameworks as precursors. Synergistic catalysis between strained platinum-cobalt core-shell nanoparticles over a platinum-group metal (PGM)–free catalytic substrate led to excellent fuel cell performance under 1 atmosphere of O2 or air at both high-voltage and high-current domains. Two catalysts achieved oxygen reduction reaction (ORR) mass activities of 1.08 amperes per milligram of platinum (A mgPt−1) and 1.77 A mgPt−1 and retained 64% and 15% of initial values after 30,000 voltage cycles in a fuel cell. Computational modeling reveals that the interaction between platinum-cobalt nanoparticles and PGM-free sites improves ORR activity and durability.
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A new high-capacity reversible hydrogen-storage material synthesized by the encapsulation of NaBH4 nanoparticles in graphene is reported. This approach effectively prevents phase agglomeration or separation during successive H2 discharge/recharge processes and enables rapid H2 uptake and release in NaBH4 under mild conditions. The strategy advanced here paves a new way for application in energy generation and storage.
In this work, a reversible hydrogen storage composite, 3NaBH 4 /NdF 3 , has been prepared using a mechanical milling method. The de-/rehydrogenation properties as well as the mechanisms of reversible hydrogen sorption in the composite were carefully investigated. Based on the pressure-temperaturecomposition measurements, the de-/rehydrogenation enthalpies of the 3NaBH 4 /NdF 3 composite are determined to be 86.4 kJ mol À1 H 2 and À13.2 kJ mol À1 H 2 , respectively. The onset dehydriding temperature of the composite is determined to be 413 C in 0.1 MPa Ar atmosphere and can be as low as 80 C under vacuum conditions. Analyses revealed that NdB 6 , Nd 2 H 5 and NaF were formed after the decomposition of the composite, which can be hydrogenated to produce NaBH 4 and NaNdF 4 . The formation of NaNdF 4 instead of NdF 3 in the hydrogenated products is believed to be responsible for the reduced hydrogen storage capacity, while the intermediate formation of B, Nd and NdB 4 during dehydrogenation accounts for the asymmetric hydriding/dehydriding behaviors in the 3NaBH 4 /NdF 3 composite.
In this work, we report the remarkable
catalytic effects of a novel
Ti3C2 MXene-based catalyst (Ni@Ti-MX), which
was prepared via self-assembling of Ni nanoparticles onto the surface
of exfoliated Ti3C2 nanosheets. The resultant
Ni@Ti-MX catalyst, characterized by ultradispersed Ni nanoparticles
being anchored on the monolayer Ti3C2 flakes,
was introduced into MgH2 through ball milling. In situ transmission electron microscopy (TEM) analysis
revealed that a synergetic catalytic effect of multiphase components
(Mg2Ni, TiO2, metallic Ti, etc.) derived in
the MgH2 + Ni@Ti-MX composite exhibits remarkable improvements
in the hydrogen sorption kinetics of MgH2. In particular,
the MgH2 + Ni@Ti-MX composite can absorb 5.4 wt % H2 in 25 s at 125 °C and release 5.2 wt % H2 in 15 min at 250 °C. Interestingly, it can uptake 4 wt % H2 in 5 h even at room temperature. Furthermore, the dehydrogenation
peak temperature of the MgH2 + Ni@Ti-MX composite is about
221 °C, which is 50 and 122 °C lower than that of MgH2 + Ti-MX and MgH2, respectively. The excellent
hydrogen sorption properties of the MgH2 + Ni@Ti-MX composite
are primarily attributed to the peculiar core–shell nanostructured
MgH2@Mg2NiH4 hybrid materials and
the interfacial coupling effects from different catalyst–matrix
interfaces. The results obtained in this study demonstrate that using
self-assembling of transition-metal elements on two-dimensional (2D)
materials as a catalyst is a promising approach to enhance the hydrogen
storage properties of MgH2.
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