Microwave has been widely used in many fields, including communication, medical treatment and military industry; however, the corresponding generated radiations have been novel hazardous sources of pollution threating human’s daily life. Therefore, designing high-performance microwave absorption materials (MAMs) has become an indispensable requirement. Recently, metal–organic frameworks (MOFs) have been considered as one of the most ideal precursor candidates of MAMs because of their tunable structure, high porosity and large specific surface area. Usually, MOF-derived MAMs exhibit excellent electrical conductivity, good magnetism and sufficient defects and interfaces, providing obvious merits in both impedance matching and microwave loss. In this review, the recent research progresses on MOF-derived MAMs were profoundly reviewed, including the categories of MOFs and MOF composites precursors, design principles, preparation methods and the relationship between mechanisms of microwave absorption and microstructures of MAMs. Finally, the current challenges and prospects for future opportunities of MOF-derived MAMs are also discussed."Image missing"

A library of tetra-substituted purine analogues was readily prepared via parallel synthesis. This strategy relies on a key cyclization of a 4,5-diaminopyrimidine with either a carboxylic acid or its derivative to construct the 2,8,9-trisubstituted 6-chloropurine core. Further elaborations of this core allow the introduction of other diversity points. This methodology is demonstrated through the preparation of a 135-membered library of tetra-substituted purines in good yields and high purity.

[reaction: see text] A novel methodology was developed for the efficient synthesis of 4-chloro-pyrimido[4,5-b][1,4]benzodiazepines. The key is the intramolecular Friedel-Crafts cyclization of 5-amino-4-(N-substituted)anilino-6-chloropyrimidine with either a carboxylic acid or its derivatives to construct the 4-chloro-pyrimido[4,5-b][1,4]benzodiazepine core. Subsequent nucleophilic substitution allows the introduction of one more diversity point in the target molecules. This strategy provides an efficient method to access a library of compounds based on privileged substructures that are of great interest in drug discovery.

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a b s t r a c tThe energy demand in China is rapidly growing, the development and applications of low energy technologies for green buildings have been paid much concern. The hollow block ventilated wall is proposed in this paper. According to the characteristic of the hollow part from up to down, the supply air passes through the cavity of the block, and then discharges to the outside after the heat exchange with the concrete hollow block, the cooling and heating requirements of envelope caused by outdoor environment can be partially removed; the building cooling/heating load can be greatly reduced or even eliminated. The Frequency-Domain Finite Difference (FDFD) model is established and the thermal performance analysis of hollow wall is carried out by using FDFD method in frequency domain. A CFD model is developed to simulate the thermal characteristics of this structure for reference for validating the FDFD model. The results demonstrate that the predictions of the FDFD and CFD models agree very well, and the FDFD model can provide accurate prediction. When the frequency varies, the frequency response of the heat flux is not obvious in low frequency region and is significant in high frequency.

We report a set of electrochemically regulated protocols for the divergent synthesis of ketones and β-keto esters from the same β-hydroxycarboxylic acid starting materials. Enabled by electrochemical control, the anodic...