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Environmental pollution caused by excessive Sb(III) in the water environment is a global issue. We investigated the effect of processing parameters, their interaction and mechanistic details for the removal of Sb(III) using an iron salt-modified biosorbent (Fe(III)-modified Proteus cibarius (FMPAs)). Our study evaluated the optimisation of the adsorption time, adsorbent dose, pH, temperature and the initial concentration of Sb(III). We use response surface methodology to optimize this process, determining optimal processing conditions and the adsorption mechanism evaluated based on isotherm model and adsorption kinetics. The results showed that—(1) the optimal conditions for the adsorption of Sb(III) by FMPAs were an adsorption time of 2.2 h, adsorbent dose of 3430 mg/L, at pH 6.0 and temperature 44.0 °C. For the optimum initial concentration of Sb(III) 27.70 mg/L, the removal efficiency of Sb(III) reached 97.60%. (2) The adsorption process for Sb(III) removal by FMPAs conforms to the Langmuir adsorption isotherm model, and its maximum adsorption capacity (qmax) is as high as 30.612 mg/g. A pseudo-first-order kinetic model provided the best fit to the adsorption process, classified as single layer adsorption and chemisorption mechanism. (3) The adsorption of Sb(III) takes place via the hydroxyl group in Fe–O–OH and EPS–Polyose–O–Fe(OH)2, which forms a new complex Fe–O–Sb and X≡Fe–OH. The study showed that FMPAs have higher adsorption capacity for Sb(III) than other previously studied sorbents and with low environmental impact, it has a great potential as a green adsorbent for Sb(III) in water.

Compared with scaled-model testing, full-scale destructive testing is more reliable since the test has no size effect and can truly record the mechanical performance of the structure. However, due to the high cost, only very few full-scale destructive tests have been conducted on the flexural behavior of prestressed concrete (PC) box girders with girders removed from decommissioned bridges. Moreover, related destructive testing on the flexural behavior of a new precast box girder has been rarely reported. To investigate the flexural behavior and optimize the design, destructive testing of a 30-meter full-scale simply supported prestressed box girder was conducted at the construction site. It is illustrated that the failure mode of the tested girder was fracture of the prestressing tendon, and the corresponding maximum compressive strain in the top flange was only 1456 μ ε , which is far less than the ultimate compressive strain (3300 μ ε ). Therefore, the concrete in the top flange was not fully utilized. A nonlinear analysis procedure was performed using the finite strip method (FSM). The validity of the analysis was demonstrated by comparing the analytical results with those of the full-scale test in the field and a scaled model test in a laboratory. Using the developed numerical method, parametric analyses of the ratio of reinforcement were carried out. The prestressing tendon of the tested girder was increased from four strands to six strands in each duct. After the optimization of the prestressed reinforcement, the girder was ductile and the bearing capacity could be increased by 44.3%.