This mini review summarizes recent progress in polydiacetylene (PDA) mechanochromism, with a special focus on the quantitative and nanoscopic data that have emerged in recent years.

Conductive polymer (CP) nanotubes are fascinating nanostructures with high electrical conductivity, fast charge/discharge capability, and high mechanical strength. Despite these attractive physical properties, progress in the synthesis of CP nanotube hydrogels is still limited. Here, we report a facile and effective approach for the synthesis of polypyrrole (PPy) nanotube hydrogels by using the weakly interconnected network of self-assembled nanotubes of lithocholic acid as a soft template. The PPy nanotube hydrogels are then converted to aerogels by freeze drying, in which PPy nanotubes form elastic and conductive networks with a density of 38 mg/cm 3 and an electrical conductivity of 1.13 S/m. The PPy nanotube aerogels are able to sustain a compressive strain as high as 70% and show an excellent cyclic compressibility due to their robust nanotube networks and hierarchically porous structures, which allow the compressive stress to be easily dissipated. Furthermore, PPy nanotube aerogels show negative strain-dependent electrical resistance changes under compressive strains. The lightweight, elastic, and conductive PPy nanotube aerogels may find potential applications in strain sensors, supercapacitors, and tissue scaffolds.

Polydiacetylene (PDA) is a popular mechanochromic material often used in biosensing. The effect of its headgroup–headgroup interactions on thermochromism such as pH or salt concentration dependency has been extensively studied before; however, their effect on mechanochromism at the nanoscale is left unstudied. In this work, nanofriction force microscopy and fluorescence microscopy were combined to study the effect of pH and ionic strength on the polydiacetylene (PDA) force sensitivity at the nanoscale. We found that the increase in pH from 5.7 to 8.2 caused an 8-fold enhancement in force sensitivity. The elevation of NaCl concentration from 10 to 200 mM also made the PDA 5 times more force-sensitive. These results suggest that the PDA force sensitivity at the nanoscale can be conveniently enhanced by “pre-stimulation” with pH or ionic strength.

The colorimetric response of polydiacetylene was observed at the single microdomain level via hyperspectral microscopy, revealing the blue-to-red transition patterns unique to each stimulus.

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