Glucose-derived water-soluble crystalline graphene quantum dots (GQDs) with an average diameter as small as 1.65 nm (∼5 layers) were prepared by a facile microwave-assisted hydrothermal method. The GQDs exhibits deep ultraviolet (DUV) emission of 4.1 eV, which is the shortest emission wavelength among all the solution-based QDs. The GQDs exhibit typical excitation wavelength-dependent properties as expected in carbon-based quantum dots. However, the emission wavelength is independent of the size of the GQDs. The unique optical properties of the GQDs are attributed to the self-passivated layer on the surface of the GQDs as revealed by electron energy loss spectroscopy. The photoluminescence quantum yields of the GQDs were determined to be 7-11%. The GQDs are capable of converting blue light into white light when the GQDs are coated onto a blue light emitting diode.
Tuning band energies of semiconductors through strain engineering can significantly enhance their electronic, photonic, and spintronic performances. Although low-dimensional nanostructures are relatively flexible, the reported tunability of the band gap is within 100 meV per 1% strain. It is also challenging to control strains in atomically thin semiconductors precisely and monitor the optical and phonon properties simultaneously. Here, we developed an electromechanical device that can apply biaxial compressive strain to trilayer MoS2 supported by a piezoelectric substrate and covered by a transparent graphene electrode. Photoluminescence and Raman characterizations show that the direct band gap can be blue-shifted for ~300 meV per 1% strain. First-principles investigations confirm the blue-shift of the direct band gap and reveal a higher tunability of the indirect band gap than the direct one. The exceptionally high strain tunability of the electronic structure in MoS2 promising a wide range of applications in functional nanodevices and the developed methodology should be generally applicable for two-dimensional semiconductors.
Two-dimensional MXenes are promising for various energy-related applications such as energy storage devices and electrocatalysis of water-splitting. MXenes prepared from hydrofluoric (HF) acid etching have been widely reported. Nonetheless, the acute toxicity of HF acid impedes the large-scale fabrication of MXenes and their wide utilization in energy-related applications. It is thus greatly encouraging to explore a more innocuous protocol for MXenes synthesis. Thereby, a universal strategy based on thermal-assisted electrochemical etching route is developed to synthesize MXenes (e.g., Ti2CT x , Cr2CT x , and V2CT x ). Furthermore, the cobalt ion doped MXenes show an exceptionally enhanced capability of hydrogen evolution reaction (HER) and oxygen evolution reaction (OER) activity, demonstrating their multifunctionalities, which is comparable to the commercialized catalysts. Moreover, we successfully exploited our MXenes as cathodes for the novel aqueous rechargeable battery, with proficient retention and excellent electrical output performance. This work paves a nontoxic and HF-free route to prepare various MXenes and demonstrates practical applications of the materials.
Ferroelectrics allow for a wide range of intriguing applications. However, maintaining ferroelectricity has been hampered by intrinsic depolarization effects. Here, by combining first-principles calculations and experimental studies, we report on the discovery of robust room-temperature out-of-plane ferroelectricity which is realized in the thinnest monolayer MoTe 2 with unexploited distorted 1T ( d 1T) phase. The origin of the ferroelectricity in d 1T-MoTe 2 results from the spontaneous symmetry breaking due to the relative atomic displacements of Mo atoms and Te atoms. Furthermore, a large ON/OFF resistance ratio is achieved in ferroelectric devices composed of MoTe 2 -based van der Waals heterostructure. Our work demonstrates that ferroelectricity can exist in two-dimensional layered material down to the atomic monolayer limit, which can result in new functionalities and achieve unexpected applications in atomic-scale electronic devices.
Large-scale synthesis of two-dimensional (2D) materials is one of the significant issues for fabricating layered materials into practical devices. As one of the typical III-VI semiconductors, InSe has attracted much attention due to its outstanding electrical transport property, attractive quantum physics characteristics, and dramatic photoresponse when it is reduced to atomic scale. However, scalable synthesis of single phase 2D InSe has not yet been achieved so far, greatly hindering further fundamental studies and device applications. Here, we demonstrate the direct growth of wafer-scale layered InSe nanosheets by pulsed laser deposition (PLD). The obtained InSe layers exhibit good uniformity, high crystallinity with macro texture feature, and stoichiometric growth by in situ precise control. The characterization of optical properties indicates that PLD grown InSe nanosheets have a wide range tunable band gap (1.26-2.20 eV) among the large-scale 2D crystals. The device demonstration of field-effect transistor shows the n-type channel feature with high mobility of 10 cm V s. Upon illumination, InSe-based phototransistors show a broad photoresponse to the wavelengths from ultraviolet to near-infrared. The maximum photoresponsivity attains 27 A/W, plus a response time of 0.5 s for the rise and 1.7 s for the decay, demonstrating the strong and fast photodetection ability. Our findings suggest that the PLD grown InSe would be a promising choice for future device applications in the 2D limit.
Upconversion control: Applying a relatively low bias voltage to an epitaxial lanthanide‐doped BaTiO3 thin film results in a significant enhancement of the upconversion emission. Moreover, the photoluminescence (PL) intensity can be modulated with an ac electric field (see picture). This approach provides a real‐time and dynamic way to control photoluminescence.
Amorphous black phosphorus (a-BP) ultrathin films are deposited by pulsed laser deposition. a-BP field-effect trans-istors, exhibiting high carrier mobility and moderate on/off current ratio, are demonstrated. Thickness dependence of the bandgap, mobility, and on/off ratio are observed. These results offer not only a new nanoscale member in the BP family, but also a new opportunity to develop nano-electronic devices.
Understanding the behaviour of the dielectric constant in ferroelectric thin films remains a challenging problem. These ferroelectric materials have high static dielectric constants, and so are important for their applications in high-storage-density capacitor structures such as dynamic random access memory (DRAM). But the dielectric constant tends to be significantly reduced in thin films, thereby limiting the potential benefit of ferroelectrics for memory devices. Extensive studies have shown that this phenomenon could be caused by a 'dead layer' of very low dielectric constant between the ferroeletric film and the electrode. And, although very few direct measurements are in fact available, it has been recognized that the lattice dynamical properties in the thin films should also play a key role in the reduction of the dielectric constant. Here we report far-infrared ellipsometry and low-frequency dielectric measurements in SrTiO3 thin films, which demonstrate that the Lyddane-Sachs-Teller relation between the optical-phonon eigenfrequencies and the dielectric constant is fully maintained, as is the case in the bulk material. This indicates that the dramatic reduction of the dielectric constant is a consequence of a profound change of the lattice dynamical properties, in particular of the reduced softening of its lowest optical-phonon mode. Our results therefore provide a better understanding of the fundamental limitations of the dielectric constant values in ferroelectric thin films.
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