The distribution of water in the Moon's interior carries key implications for the origin of the Moon 1 , the crystallisation of the lunar magma ocean 2 , and the duration of lunar volcanism 2 . The Chang'E-5 (CE5) mission returned the youngest mare basalt samples, dated at ca. 2.0 billion years ago 3 , from the northwestern Procellarum KREEP Terrane (PKT), providing a probe into the spatio-temporal evolution of lunar water. Here we report the water abundance and hydrogen isotope composition of apatite and ilmenite-hosted melt inclusions from CE5 basalts, from which we derived a maximum water abundance of 370 ± 30 g.g -1 and a δD value (-330 ± 160‰) for their parent magma. During eruption, hydrogen degassing led to an increase in the D/H ratio of the residual melts up to δD values of 300-900‰. Accounting for low degrees of mantle partial melting followed by extensive magma fractional crystallisation 4 , we estimate a maximum mantle water abundance of 2-6 g.g -1 , which are too low for water contents alone to account for generating the Moon's youngest basalts. Such modest water abundances for the lunar mantle are at the lower end of those estimated from mare basalts that erupted from ca. 4.0-2.8 Ga 5, 6 , suggesting the mantle source of CE5 basalts dried up by ca. 2.0 Ga through previous melt extraction from the PKT mantle during prolonged volcanic activity.Water abundance in the lunar mantle places strict constraints on high-temperature processes, including the Moon-forming giant impact 1 , the ensuing crystallisation of the lunar magma ocean 7 , and the longevity of volcanism on the Moon 2 . Based upon the analyses carried out since the Apollo era, the Moon was long thought to be an anhydrous body. Advances in in situ analytical techniques over the past decade have allowed analysis of water abundances at micro-scale in various lunar samples, including in olivine-and pyroxene-hosted melt inclusions in mare basalts [8][9][10][11][12] , apatite in mare basalts and highlands samples [13][14][15][16][17][18][19][20] , pyroclastic glass beads 21, 22 , and
The past two decades of lunar exploration have seen the detection of substantial quantities of water on the Moon’s surface. It has been proposed that a hydrated layer exists at depth in lunar soils, buffering a water cycle on the Moon globally. However, a reservoir has yet to be identified for this hydrated layer. Here we report the abundance, hydrogen isotope composition and core-to-rim variations of water measured in impact glass beads extracted from lunar soils returned by the Chang’e-5 mission. The impact glass beads preserve hydration signatures and display water abundance profiles consistent with the inward diffusion of solar wind-derived water. Diffusion modelling estimates diffusion timescales of less than 15 years at a temperature of 360 K. Such short diffusion timescales suggest an efficient water recharge mechanism that could sustain the lunar surface water cycle. We estimate that the amount of water hosted by impact glass beads in lunar soils may reach up to 2.7 × 1014 kg. Our direct measurements of this surface reservoir of lunar water show that impact glass beads can store substantial quantities of solar wind-derived water on the Moon and suggest that impact glass may be water reservoirs on other airless bodies.
This paper first reports a Pb-Pb and U-Pb analytical method at a sub-micron scale using NanoSIMS equipped with the new radio-frequency (RF) ion source. The RF ion source can generate...
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