Start of growing season advanced by 9.4 ± 2.2 and 8.3± 2.0 days during 1982-1999 and 2000-2020 respectively, whereas its end delayed only by 8.2 ± 1.9 days during 2000-2020.Current models project an advance in season start by 8.8 days and a delay in season end by 14.0 days in 2086-2100 relative to 2000-2014 under Shared-Socioeconomic-Pathway 5-8.5. Warming and increasing precipitation are the main climatic drivers of advancing spring phenology (start of vegetative growing season and first flowering) and delaying end of the growing season. The direction and magnitude of responses of phenophases to temperature depend on soil water availability, with greater temperature sensitivity of the start and end of the season under wetter conditions.First flowering date is more sensitive to temperature on the Qinghai-Tibetan Plateau than in Arctic grasslands.The temperature sensitivities of the start and end of the growing season are greater than those of Arctic grasslands, but smaller than those of mid-latitude alpine and subalpine grasslands.
Great progress has been achieved in the research field of topological states of matter during the past decade. Recently, a quasi–1-dimensional bismuth bromide, Bi4Br4, has been predicted to be a rotational symmetry-protected topological crystalline insulator; it would also exhibit more exotic topological properties under pressure. Here, we report a thorough study of phase transitions and superconductivity in a quasihydrostatically pressurized α-Bi4Br4 crystal by performing detailed measurements of electrical resistance, alternating current magnetic susceptibility, and in situ high-pressure single-crystal X-ray diffraction together with first principles calculations. We find a pressure-induced insulator–metal transition between ∼3.0 and 3.8 GPa where valence and conduction bands cross the Fermi level to form a set of small pockets of holes and electrons. With further increase of pressure, 2 superconductive transitions emerge. One shows a sharp resistance drop to 0 near 6.8 K at 3.8 GPa; the transition temperature gradually lowers with increasing pressure and completely vanishes above 12.0 GPa. Another transition sets in around 9.0 K at 5.5 GPa and persists up to the highest pressure of 45.0 GPa studied in this work. Intriguingly, we find that the first superconducting phase might coexist with a nontrivial rotational symmetry-protected topology in the pressure range of ∼3.8 to 4.3 GPa; the second one is associated with a structural phase transition from monoclinic C2/m to triclinic P-1 symmetry.
At ambient pressure CrAs undergoes a first-order transition into a double-helical magnetic state at TN = 265 K, which is accompanied by a structural transition. The recent discovery of pressureinduced superconductivity in CrAs makes it important to clarify the nature of quantum phase transitions out of its coupled structural/helimagnetic order. Here we show, via neutron diffraction on the single-crystal CrAs under hydrostatic pressure (P), that the combined order is suppressed at Pc 10 kbar, near which bulk superconductivity develops with a maximal transition temperature Tc 2 K. We further show that the coupled order is also completely suppressed by phosphorus doping in CrAs1-xPx at a critical xc 0.05, above which inelastic neutron scattering evidenced persistent antiferromagnetic correlations, providing a possible link between magnetism and superconductivity. In line with the presence of antiferromagnetic fluctuations near Pc (xc), the A coefficient of the quadratic temperature dependence of resistivity exhibits a dramatic enhancement as P (x) approaches Pc (xc), around which (T) has a non-Fermi-liquid form. Accordingly, the electronic specific-heat coefficient of CrAs1-xPx peaks out around xc.These properties provide clear evidences for quantum criticality, which we interpret as originating from a nearly second-order helimagnetic quantum phase transition that is concomitant with a first-order structural transition. Our findings in CrAs highlight the distinct characteristics of quantum criticality in bad metals, thereby bringing out new insights into the physics of unconventional superconductivity such as occurring in the high-Tc iron pnictides.
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