Radiative cooling is a passive cooling strategy with zero consumption of electricity, and it can be used to radiate heat from buildings to reduce air conditioning requirements. Although this technology can work well during optimal atmospheric conditions at nighttime, it is essential to achieve efficient cooling during daytime when peak cooling demand actually occurs. In this article, we report an inexpensive planar polydimethylsiloxane (PDMS)/metal thermal emitter, i.e., a thin film structure, which was fabricated using a fast solution coating process that is scalable for large area manufacturing. By performing tests under different environmental conditions, temperature reductions of 9.5 °C and 11.0 °C were demonstrated in the laboratory and outdoor environment, respectively, with an average cooling power of ~120 W/m 2 for the thin film thermal emitter. In addition, a spectral-selective structure was designed and implemented to suppress the solar input and control the divergence of the thermal emission beam. This enhanced the directionality of the thermal emissions, so the emitter's cooling performance was less dependent on the surrounding environment. Outdoor experiments were performed in Buffalo NY realizing continuous allday cooling of 2~9 °C on a typical clear sunny day at Northern United States latitudes. This practical strategy that cools without electricity input could have a significant impact on global energy consumption.
Copper(I)
thiocyanate (CuSCN) is a wide bandgap and solution-processable p-type semiconductor with tremendous potential for large-area
optoelectronic applications. In this work, chlorine-doped CuSCN (Cl2–CuSCN) was utilized to form a hole transport layer
(HTL) for different organic solar cells (OSCs) and inverted perovskite
solar cells (PSCs). Chlorine doping into CuSCN thin films is found
to improve the device performance of different OSCs, to a level comparable
to that of PEDOT:PSS-based OSCs. Notably, the inverted PSCs with Cl2–CuSCN showed a better performance than those with
pristine CuSCN or PEDOT:PSS-based inverted PSC devices. Moreover,
Cl2–CuSCN-based OSCs and PSCs also reveal significantly
better stability than pristine CuSCN and PEDOT:PSS-based devices.
Our results show how Cl2–CuSCN thin films act as
a universally applicable HTL for emerging solar cell technologies,
improving both device performance and stability.
Copper thiocyanate
(CuSCN) is a p-type semiconductor that exhibits
hole-transport and wide-band gap (∼3.9 eV) characteristics.
However, the conductivity of CuSCN is not sufficiently high, which
limits its potential application in optoelectronic devices. Herein,
CuSCN thin films were exposed to chlorine using a dry etching system
to enhance their electrical properties, yielding a maximum hole concentration
of 3 × 10
18
cm
–3
. The p-type CuSCN
layer was then deposited onto an n-type gallium nitride (GaN) layer
to form a prototypical ultraviolet-based photodetector. X-ray photoelectron
spectroscopy further demonstrated the interface electronic structures
of the heterojunction, confirming a favorable alignment for holes
and electrons transport. The ensuing p-CuSCN/n-GaN heterojunction
photodetector exhibited a turn-on voltage of 2.3 V, a responsivity
of 1.35 A/W at −1 V, and an external quantum efficiency of
5.14 × 10
2
% under illumination with ultraviolet light
(peak wavelength of 330 nm). The work opens a new pathway for making
a plethora of hybrid optoelectronic devices of inorganic and organic
nature by using p-type CuSCN as the hole injection layer.
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