Global sea surface salinity (SSS) has been obtained from space since 2009 by the Soil Moisture and Ocean Salinity (SMOS) mission and has been further enhanced by Aquarius in 2011 and Soil Moisture Active‐Passive (SMAP) missions in 2015. Due to the differences between SMOS, Aquarius, and SMAP in the instruments used, retrieval algorithms, and error correction strategies, the quality of their gridded products are different. In this paper, we have assessed the accuracy of three satellite products using in situ gridded data and buoy data. Compared with gridded in situ salinity measurements, the monthly Aquarius data are of the best quality, reaching the mission target accuracy (0.2 PSU) in the open ocean. SMOS and SMAP agree well with in situ data in the open ocean between 40°S and 40°N (root‐mean‐square deviation [RMSD]: SMOS 0.211 PSU, SMAP 0.233 PSU). The RMSD of SMAP is lower than that of SMOS at high latitudes, which may due to the fact that the roughness correction of SMAP is based on the Aquarius geophysical model function. Meanwhile, time series comparison of salinity measured at 1 m by moored buoys indicates that satellite SSS captures variability of SSS at weekly time scales with reasonably good accuracy (RMSD: SMOS 0.25 PSU, SMAP 0.26 PSU), when excluding suspicious buoy data. Synergetic analysis of satellite SSS and Argo data indicates that satellite SSS can be applied as real‐time quality control of buoy 1‐m salinity data.
Cancer imaging requires biocompatible and bright contrast-agents with selective and high accumulation in the tumor region but low uptake in normal tissues. Herein, 1-methyl-2-pyrrolidinone (NMP)-derived polymer-coated nitrogen-doped carbon nanodots (pN-CNDs) with a particle size in the range of 5-15 nm are prepared by a facile direct solvothermal reaction. The as-prepared pN-CNDs exhibit stable and adjustable fluorescence and excellent water solubility. Results of a cell viability test (CCK-8) and histology analysis both demonstrate that the pN-CNDs have no obvious cytotoxicity. Most importantly, the pN-CNDs can expediently enter glioma cells in vitro and also mediate glioma fluorescence imaging in vivo with good contrast via elevated passive targeting.
A proof-of-concept study demonstrated the feasibility of a novel gel-pad microarray on porous silicon chips, by initiation of an atom transfer radical propagation (ATRP) polymerisation of (polyethylene glycol) methacrylate (PEGMA) with surface Si-H species, stepwise chemical conversions of the gel membrane to an NTA-Ni2+/histidine-tagged protein system, and matrix-assisted laser desorption/ionisation mass spectroscopy (MALDI MS) and fluorescence detections.
In this work, a density functional approach was applied to describe the interfacial thermodynamic properties of CO 2 binary mixtures including CO 2 + heptane, CO 2 + acetone, CO 2 + ethanol, and CO 2 + water. In the theoretical model, the first-order mean spherical approximation statistical associating fluid theory (FMSA-SAFT) was incorporated to describe the chemical potential of the bulk term, while, for inhomogeneous potential, the modified fundamental measure theory (MFMT) was employed to describe the hard sphere contribution, and a weighted density approximation was adopted for the attractive contribution. Without any adjustable parameter, the theoretical calculations have been well-testified by the available experimental data, showing a good predictive capability of the theory to the interfacial structure and tensions of CO 2 binary mixtures with nonpolar, polar, and associating fluids.
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