Coal
and biomass co-combustion in existing utility boilers is a
promising option of mitigating the fossil energy crisis and reducing
the gaseous emissions of NO
x
, SO
x
, and CO2. However, ash-related problems,
including fouling, slagging, and corrosion cause damage to the heat
exchange tube and reduce boiler efficiency. In an attempt to give
better insights into the slagging behavior during coal/biomass combustion,
an experimental investigation was conducted to study the growth of
slag when coal was co-fired with wood and corn stalk in a 300 kW pilot-scale
furnace. For comparison, combustion of pure coal was also conducted.
During the experiments, biomass proportions of 5 and 10% by weight
were examined. Slags formed on an oil-cooled deposition probe were
collected, sampled, and analyzed using scanning electron microscopy
and X-ray diffraction (XRD). The change in slag thickness with time
was obtained by a charge-coupled device monitoring system. With two
thermocouples in the probe, the heat flux through the slag could be
measured. The slag from pure coal combustion showed a layered structure
with different levels of compactness and hardness. The heat flux decreased
by 31.7% as the slag grew to 5.19 mm. The results showed that co-firing
wood significantly inhibited the slagging behavior. Especially in
the 10% wood case, hardly any slag was collected from the probe. Nevertheless,
co-firing corn stalk resulted in severe slagging, with a slag thickness
of 5.5 and 6.1 mm for two blend ratios. The formation of bubbles in
the deposits together with greater deposit thickness caused heat transfer
deterioration. XRD results revealed that the influence of co-firing
biomass and corn stalk caused quite different changes to mineral species
from wood. It was observed that fly ash under different biomass co-firing
conditions differed little on mineral compositions.
Understanding the reduction mechanism of additives on ammonium bisulfate (ABS) fouling formation can alleviate ABS fouling problems. This paper presents an investigation of the influence of Na 2 SO 3 /NaHSO 3 on the formation process of ABS fouling with an in situ measurement technique. According to the thickness curves, both Na 2 SO 3 and NaHSO 3 can control the growth of ABS fouling, but Na 2 SO 3 shows a better inhibitory effect on the growth of ABS fouling. Meanwhile, the mitigation effect of the additive on ABS fouling increases with the increasing injection quantity of the additive. The results of the heat flux show that the heat transfer performance of the fouling probe becomes better with the injection of additives, whereas the heat transfer performance becomes worse with the increasing injection quantity of additives. The thermal resistance of ABS fouling provides a reasonable agreement with the results of the heat flux. The SEM-EDX results show that the additives have an effect on the formation of ABS fouling by controlling the ABS concentration, which can increase the viscosity of the particle, promote the agglomeration of the fouling particle, and enhance the heat transfer of the ABS fouling, providing a rational explanation for the experimental results.
KEYWORDSadditive, effective thermal conductivity, in situ measurement, low-temperature ash deposition
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