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Lithium-ion batteries have always been a focus of research on new energy vehicles, however, their internal reactions are complex, and problems such as battery aging and safety have not been fully understood. In view of the research and preliminary application of the digital twin in complex systems such as aerospace, we will have the opportunity to use the digital twin to solve the bottleneck of current battery research. Firstly, this paper arranges the development history, basic concepts and key technologies of the digital twin, and summarizes current research methods and challenges in battery modeling, state estimation, remaining useful life prediction, battery safety and control. Furthermore, based on digital twin we describe the solutions for battery digital modeling, real-time state estimation, dynamic charging control, dynamic thermal management, and dynamic equalization control in the intelligent battery management system. We also give development opportunities for digital twin in the battery field. Finally we summarize the development trends and challenges of smart battery management.