Four A2B type cobalt triaryl corrole complexes (1-4) bearing aldehyde and pyridyl substituents at the 10-meso-phenyl group with different spatial configuration had been synthesized and well characterized by HR-MS, NMR,...
ABSTRACT:The synthesis of three low symmetry A 2 B type Mn(III)triarylcorroles with mesoaryl substituents that provide push-pull electrondonating and withdrawing properties is reported. An analysis of the structureproperty relationships for the optical and redox properties has been carried out through a comparison with the results of theoretical calculations. The results demonstrate that A 2 B type Mn(III)triarylcorroles interact strongly with cellfree circulating tumor deoxyribonucleic acid (ctDNA) in solution, and that the interaction constants are enhanced when a stronger electrondonating substituent is introduced at the 10position of the mesotriarylcorrole ligand.
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