3D petal-like NiCo2S4 nanostructures have been fabricated via a simple, mild and efficient hydrothermal strategy and the growth mechanism of NiCo2S4 nano-petals has been investigated.
In this work, an environmentally friendly and novel oxide-based mechanoluminescent material, Sr 3 Al 2 O 6 : Eu 3+ , which can serve as the alternative for the widely used but environmentally hazardous transition metal-doped sulfides is reported. This oxide could exhibit highly efficient photoluminescence, but even more efficient mechanoluminescence as embedded into polydimethylsiloxane matrix under mechanical stimulation. The emitting color of the resultant Sr 3 Al 2 O 6 : Eu 3+ /polydimethylsiloxane elastomer composites could be further manipulated by adjusting the synthesis atmosphere of the Sr 3 Al 2 O 6 : Eu 3+ based on its unique self-reduction characteristic. Moreover, by combining the wavelength selectivity of photoluminescence and dynamic stress response of mechanoluminescence, Sr 3 Al 2 O 6 : Eu 3+ enables the design of two types of intriguing devices. They are a dualresponsive anticounterfeiting flexible device activated by either photons or mechanics, and a comprehensive stretching/strain sensor capable of sensing both strain level and stretching states. In comparison to the conventional luminescent materials, with a rare combination of efficient photoluminescence, highly sensitive mechanoluminescence, and facile color tunability, Sr 3 Al 2 O 6 : Eu 3+ is much more versatile and ideal for various advanced applications.
Wearable textile energy storage systems are rapidly growing, but obtaining carbon fiber fabric electrodes with both high capacitances to provide a high energy density and mechanical strength to allow the material to be weaved or knitted into desired devices remains challenging. In this work, N/O‐enriched carbon cloth with a large surface area and the desired pore volume is fabricated. An electrochemical oxidation method is used to modify the surface chemistry through incorporation of electrochemical active functional groups to the carbon surface and to further increase the specific surface area and the pore volume of the carbon cloth. The resulting carbon cloth electrode presents excellent electrochemical properties, including ultrahigh areal capacitance with good rate ability and cycling stability. Furthermore, the fabricated symmetric supercapacitors with a 2 V stable voltage window deliver ultrahigh energy densities (6.8 mW h cm−3 for fiber‐shaped samples and 9.4 mW h cm−3 for fabric samples) and exhibit excellent flexibility. The fabric supercapacitors are further tested in a belt‐shaped device as a watchband to power an electronic watch for ≈9 h, in a heart‐shaped logo to supply power for ≈1 h and in a safety light that functions for ≈1 h, indicating various promising applications of these supercapacitors.
An intriguing mechanics-induced triple-mode anticounterfeiting device and a moving tactile sensor were developed by simultaneously utilizing transient and persistent mechanoluminescence.
The development and application of aqueous zinc-ion batteries still face some obstacles, such as dendrite growth and side reactions triggered by active water. Here, we constructed PVA@SR-ZnMoO4 multifunctional coating on...
Anticounterfeiting
is a highly required technique to protect the
product and the consumer rights in the modern society. The conventional
luminescent anticounterfeiting is based on downconversion luminescence
excited by an ultraviolet light, which is easy to be faked. In this
work, we realized six luminescent modes in a niobate-based structure
(LiNbO3:RE3+, RE3+ = Pr3+, Tm3+, Er3+, Yb3+), in which photostimulated
luminescence of LiNbO3:Pr3+, and upconversion
luminescence color evolution of LiNbO3:Er3+ were
first presented. Based on the above luminescent modes of LiNbO3:RE3+, multilevel anticounterfeiting devices were
developed. By employing mechanoluminescence and persistent luminescence,
we achieved dual-mode anticounterfeiting that could display the luminescent
patterns without any direct irradiation. In addition, another dual-mode
anticounterfeiting based on photostimulated luminescence and upconversion
luminescence excited by a near-infrared light was realized, which
could display the anticounterfeiting patterns in both static and dynamic
states. To obtain an even higher anticounterfeiting level, downconversion
luminescence, thermoluminescence, photostimulated luminescence, and
upconversion luminescence were simultaneously applied in a food trademark.
This four-mode anticounterfeiting trademark could not only show a
static–dynamic luminescence that is hard to be faked but also
allow consumers to distinguish the food freshness. The presented multilevel
anticounterfeiting strategies could be employed to resolve the counterfeit
issues in various fields.
scite is a Brooklyn-based organization that helps researchers better discover and understand research articles through Smart Citations–citations that display the context of the citation and describe whether the article provides supporting or contrasting evidence. scite is used by students and researchers from around the world and is funded in part by the National Science Foundation and the National Institute on Drug Abuse of the National Institutes of Health.