Primary and secondary sources contributing to atmospheric organic aerosol during the months of July and August were quantitatively assessed in three North American urban areas: Cleveland, Ohio, and Detroit, Michigan, in the Midwest region and Riverside, California, in the Los Angeles Air Basin. Organic molecular marker species unique to primary aerosol sources and secondarytracers derived from isoprene, alpha-pinene, beta-caryophyllene, and toluene were measured using gas chromatography-mass spectrometry. Source contributions from motor vehicles, biomass burning, vegetative detritus, and secondary organic aerosol (SOA) were estimated using chemical mass balance (CMB) modeling. In Cleveland, primary sources accounted for 37 +/- 2% of ambient organic carbon, measured biogenic and anthropogenic secondary sources contributed 46 +/- 6%, and other unknown sources contributed 17 +/- 4%. Similarly, Detroit aerosol was determined to be 44 +/- 5% primary and 37 +/- 3% secondary, while 19 +/- 7% was unaccounted for by measured sources. In Riverside, 21 +/- 3% of organic carbon came from primary sources, 26 +/- 5% was attributed to measured secondary sources, and 53 +/- 3% came from other sources that were expected to be secondary in nature. The comparison of samples across these two regions demonstrated that summertime SOA in the Midwestern United States was substantially different from the summertime SOA in the Los Angeles Air Basin and indicated the need to exert caution when generalizing about the sources and nature of SOA across different urban areas. Furthermore, the results of this study suggestthatthe contemporary understanding of SOA sources and formation mechanisms is satisfactory to explainthe majority of SOA in the Midwest Additional SOA sources and mechanisms of formation are needed to explain the majority of SOA in the Los Angeles Air Basin.
Porous micro- and nanostructured materials with desired morphologies and tunable pore sizes are of great interests because of their potential applications in environmental remediation. In this study, novel rattle-type carbon-alumina core-shell spheres were prepared by using glucose and metal salt as precursors via a simple one-pot hydrothermal synthesis followed by calcination. The microstructure, morphology, and chemical composition of the resulting materials were characterized by X-ray diffraction (XRD), energy dispersive X-ray spectroscopy (EDX), scanning electron microscopy (SEM), transmission electron microscopy (TEM), and N(2) adsorption-desorption techniques. These rattle-type spheres are composed of a porous Al(2)O(3) shell (thickness ≈ 80 nm) and a solid carbon core (diameter ≈ 200 nm) with variable space between the core and shell. Furthermore, adsorption experiments indicate that the resulting carbon-alumina particles are powerful adsorbents for the removal of Orange-II dye from water with maximum adsorption capacity of ~210 mg/g. It is envisioned that these rattle-type composite particles with high surface area and large cavities are of particular interest for adsorption of pollutants, separation, and water purification.
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