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Thanks to the high theoretical capacity and energy density, abundant resource, low-cost, and environmental friendliness, aluminum-air battery (AAB) has attracted research interests driven by the promise for electricity generator. However, low operating voltage leads to low practical energy density, and restricting the applications of AAB. In this study, the concept of an ultrahigh voltage AAB based on aqueous alkaline-acid hybrid electrolyte is introduced and demonstrated. Meanwhile, the working mechanism is investigated. And the open-circuit voltage of the novel designed battery is 2.56 V, 29.9% higher than conventional alkaline AAB. Thanks to the fluid electrolyte, the decline in discharge voltage caused by the change in pH is overcome. And a high-energy density of 4591 mWh g Al −1 is achieved at a discharge voltage of around 2.08 V at 10 mA cm −2. These results provide a viable approach to improve the performance of Al-air battery.

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Summary Numerical simulation is widely used in research and design of the battery thermal management system (BTMS). Battery cells are commonly homogenized to a block for module or pack level modeling. However, how the homogenization method affects results is not proven. This paper works on a hard‐cased Li‐ion battery to find a proper simplification method. First, a detailed three‐dimensional thermal model (model A) is set up and validated by experimental data. Then, the other three models with different simplification strategies are proposed. They are model B (the cell is homogenized to a block), model C (the cell preserves only core region and housing case), and model D (based on model C, the thin insulation films are also considered). Take the results of model A as a reference, the calculation accuracy and efficiency are summarized. It is found that model B shows the best efficiency and is a proper choice for evaluation of temperature dynamics, while model D is more recommended when the internal temperature distribution of the battery is more concerned.