Thermal energy was shown to be efficiently converted into electrical power in a thermally regenerative ammonia-based battery (TRAB) using copper-based redox couples [Cu(NH 3 ) 4 2+ /Cu and Cu(II)/Cu].Ammonia addition to the anolyte (2 M ammonia in a copper-nitrate electrolyte) of a single TRAB cell produced a maximum power density of 115 AE 1 W m À2 (based on projected area of a single copper mesh electrode), with an energy density of 453 W h m À3 (normalized to the total electrolyte volume, under maximum power production conditions). Adding a second cell doubled both the voltage and maximum power. Increasing the anolyte ammonia concentration to 3 M further improved the maximum power density to 136 AE 3 W m À2 . Volatilization of ammonia from the spent anolyte by heating (simulating distillation), and re-addition of this ammonia to the spent catholyte chamber with subsequent operation of this chamber as the anode (to regenerate copper on the other electrode), produced a maximum power density of 60 AE 3 W m À2 , with an average discharge energy efficiency of $29%(electrical energy captured versus chemical energy in the starting solutions). Power was restored to 126 AE 5 W m À2 through acid addition to the regenerated catholyte to decrease pH and dissolve Cu(OH) 2 precipitates, suggesting that an inexpensive acid or a waste acid could be used to improve performance.These results demonstrated that TRABs using ammonia-based electrolytes and inexpensive copper electrodes can provide a practical method for efficient conversion of low-grade thermal energy into electricity.
Broader contextThe utilization of waste heat for power production would enable additional electricity generation without any additional consumption of fossil fuels. Thermally regenerative batteries (TRBs) allow a carbon neutral approach for the storage and conversion of waste heat into electrical power, with potentially lower costs than solid-state devices. Here we present a highly efficient, inexpensive, and scalable ammonia-based TRB (TRAB) where electrical current is produced from the formation of copper ammonia complex. The ammonia can then be captured and concentrated by distillation of the anolyte, allowing recharge of the system. The voltage created by ammonia addition in the anolyte results in copper deposition onto the cathode, and loss of copper from the anode. However, by reversing the function of electrodes in the next cycle, there is no net loss of copper. With a 3 M anolyte ammonia, a TRAB produced the highest power density ever obtained for an aqueous-based, thermoelectrochemical system, of 136 AE 3 W m À2 . This power density was substantially higher than those produced using salinity gradient energy technologies based on generating salty and less-salty solutions using waste heat. This TRAB technology therefore represents a new and promising approach for efficient harvesting of low-grade waste heat as electrical power.
Multimodal
molecular imaging has shown promise as a complementary
approach to thrombus detection. However, the simultaneous noninvasive
detection and lysis of thrombi for cardiovascular diseases remain
challenging. Herein, a perfluorohexane (PFH)-based biocompatible nanostructure
was fabricated, namely, as-prepared Fe3O4-poly(lactic-co-glycolic acid)-PFH-CREKA nanoparticles (NPs), which combine
phase transition (PT) thrombolysis capabilities with properties conducive
to multimodal imaging. This well-developed PT agent responded effectively
to low-intensity focused ultrasound (LIFU) by triggering the vaporization
of liquid PFH to achieve thrombolysis. The presence of the CREKA peptide,
which binds to the fibrin of the thrombus, allows targeted imaging
and efficacious thrombolysis. Then, we found that, compared with thrombolysis
using a non-phase-transition agent, PT thrombolysis can produce a
robust decrease in the thrombus burden regardless of the acoustic
power density of LIFU. In particular, the reduced energy for LIFU-responsive
PT during the lysis process guarantees the superior safety of PT thrombolysis.
After injecting the NPs intravenously, we demonstrated that this lysis
process can be monitored with ultrasound and photoacoustic imaging in vivo to evaluate its efficacy. Therefore, this nonpharmaceutical
strategy departs from routine methods and reveals the potential use
of PT thrombolysis as an effective and noninvasive alternative to
current thrombolytic therapy.
Activated carbon (AC) is a low‐cost and effective catalyst for oxygen reduction in air cathodes of microbial fuel cells (MFCs), but its performance must be maintained over time. AC was modified by three methods: 1) pyrolysis with iron ethylenediaminetetraacetic acid (AC‐Fe), 2) heat treatment (AC‐heat), and 3) mixing with carbon black (AC‐CB). The maximum power densities after one month with these AC cathodes were 35 % higher with AC‐Fe (1410±50 mW m−2) and AC‐heat (1400±20 mW m−2), and 16 % higher with AC‐CB (1210±30 mW m−2) than for plain AC (1040±20 mW m−2), versus 1270±50 mW m−2 for a Pt control. After 16 months, the Pt cathodes produced only 250±10 mW m−2. However, the AC‐heat and AC‐CB cathodes still produced 960–970 mW m−2, whereas plain AC produced 860±60 mW m−2. The performance of the AC cathodes was restored to >85 % of the initial maximum power densities by cleaning with a weak acid solution. Based on cost considerations among the AC materials, AC‐CB appears to be the best choice for long‐term performance.
A thermally regenerative ammonia battery (TRAB) is a new approach for converting low-grade thermal energy into electricity by using an ammonia electrolyte and copper electrodes. TRAB operation at 72 °C produced a power density of 236 ± 8 Wm(-2), with a linear decrease in power to 95 ± 5 Wm(-2) at 23 °C. The improved power at higher temperatures was due to reduced electrode overpotentials and more favorable thermodynamics for the anode reaction (copper oxidation). The energy density varied with temperature and discharge rates, with a maximum of 650 Wh m(-3) at a discharge energy efficiency of 54% and a temperature of 37 °C. The energy efficiency calculated with chemical process simulation software indicated a Carnot-based efficiency of up to 13% and an overall thermal energy recovery of 0.5%. It should be possible to substantially improve these energy recoveries through optimization of electrolyte concentrations and by using improved ion-selective membranes and energy recovery systems such as heat exchangers.
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