In an effort to fabricate a wearable piezoelectric energy harvester based on core-shell piezoelectric yarns with external electrodes, flexible piezoelectric nanofibers of BNT-ST (0.78Bi0.5Na0.5TiO3-0.22SrTiO3) and polyvinylidene fluoride-trifluoroethylene (PVDF-TrFE) were initially electrospun. Subsequently, core-shell piezoelectric nanofiber yarns were prepared by twining the yarns around a conductive thread. To create the outer electrode layers, the core-shell piezoelectric nanofiber yarns were braided with conductive thread. Core-shell piezoelectric nanofiber yarns with external electrodes were then directly stitched onto the fabric. In bending tests, the output voltages were investigated according to the total length, effective area, and stitching interval of the piezoelectric yarns. Stitching patterns of the piezoelectric yarns on the fabric were optimized based on these results. The output voltages of the stitched piezoelectric yarns on the fabric were improved with an increase in the pressure, and the output voltage characteristics were investigated according to various body movements of bending and pressing conditions.
Piezoelectric nanofiber composites of polyvinylidene fluoride (PVDF) polymer and PZT (Pb(Zr 0.53 Ti 0.47 )O 3 ) ceramics were fabricated by electrospinning. The microstructure of the PZT/PVDF electrospun nanofiber composites was characterized using X-ray diffraction (XRD), scanning electron microscopy (SEM) and transmission electron microscopy (TEM). The tensile properties (stressstrain curves) and electrical properties (P-E hysteresis loops) of the PZT/PVDF electrospun nanofiber composites were investigated as a function of PZT content from 0 wt% to 30 wt%. The results demonstrated that a PZT content of 20 wt % had enhanced tensile and piezoelectric characteristics.
An all-in-one energy
harvester module comprising a top piezoelectric
layer, a bottom piezoelectric layer, and a middle triboelectric layer
was fabricated based on flexible piezoceramic nanofibers to serve
as a power source for wearable devices. The top and bottom piezoelectric
layers were manufactured by modularizing electrospun piezoceramic
nanofibers with an interdigitated electrode, and the energy harvesting
characteristics were maximized by laminating the single modules in z-axis array arrangements. The triboelectric layer was manufactured
by attaching polydimethylsiloxane on both sides of an electrode layer,
and the energy harvesting characteristics were controlled according
to the surface roughness of the triboelectric modules. The output
voltages of the individual energy harvester modules of the all-in-one
module were individually or integrally measured by hand pressing the
lower and upper parts of the module. The all-in-one energy harvester
module generated a maximum voltage (power) of 253 V (3.8 mW), and
the time required to charge a 0.1 μF capacitor to 25 V was 40
s. The results of a simulated energy harvesting experiment conducted
on the all-in-one energy harvester module showed that 42 LED bulbs
arranged in the shape of the “KICET” logo could be turned
on in real time without charging, and a mini fan consuming a power
of 3.5 W was operated after charging a 10 μF capacitor for 250
s. This work shows the potential of the all-in-one module as an ecofriendly
flexible energy harvester for operating wearable devices.
Silane coupling agents (SCAs) with different organofunctional groups were coated on the surfaces of Al2O3 ceramic particles through hydrolysis and condensation reactions, and the SCA-coated Al2O3 ceramic particles were dispersed in a commercial photopolymer based on interpenetrating networks (IPNs). The organofunctional groups that have high radical reactivity and are more effective in UV curing systems are usually functional groups based on acryl, such as acryloxy groups, methacrloxy groups, and acrylamide groups, and these silane coupling agents seem to improve interfacial adhesion and dispersion stability. The coating morphology and the coating thickness distribution of SCA-coated Al2O3 ceramic particles according to the different organofunctional groups were observed by FE-TEM. The initial dispersibility and dispersion stability of the SCA-coated Al2O3/High-temp composite solutions were investigated by relaxation NMR and Turbiscan. The rheological properties of the composite solutions were investigated by viscoelastic analysis and the mechanical properties of 3D-printed objects were observed with a nanoindenter.
Al 2 O 3 ceramic-reinforced photopolymer samples for SLA 3D printing technology were prepared using a silane coupling agent (VTES, vinyltriethoxysilane). Depending on the method used to coat the VTES onto the ceramic surface, the dispersion of ceramic particles in the photopolymer solution was remarkably improved. SEM, TEM and element mapping images showed Al 2 O 3 particles well wrapped with VTES along with well-distributed Al 2 O 3 particles overall on the cross-sectional surfaces of 3D-printed objects. The tensile properties (stress-strain curves) of 3D-printed objects of the ceramic-reinforced photopolymer were investigated as a function of the Al 2 O 3 ceramic content when it ranged from 0 to 20 wt%. The results demonstrate that an Al 2 O 3 ceramic content of 15 wt% resulted in enhanced tensile characteristics.
A 3YSZ (3 mol% yttria-stabilized zirconia) ceramic green body with 50 vol% of ceramic content was 3D-printed by supportless stereolithography under optimal drying, debinding, and sintering conditions in order to achieve high strength and density. The viscosity and flowability of the ceramic nanocomposite resins were optimized by adjusting the amounts of non-reactive diluents. The ceramic 3D-printed objects have a high polymer content compared to ceramics samples manufactured by conventional manufacturing processes, and the attraction between layers is weak because of the layer-by-layer additive method. This causes problems such as layer separation and cracking due to internal stress generated when materials such as solvents and polymers are separated from the objects during the drying and debinding processes; therefore, the drying and debinding conditions of 3YSZ ceramic 3D-printed objects were optimized based on thermogravimetry–differential thermal analysis. The sintering conditions at various temperatures and times were analyzed using X-ray diffraction, SEM, and flexural strength analysis, and the body of the 3YSZ ceramic 3D-printed object that sintered at 1450 °C for 150 min had a relative density of 99.95% and flexural strength of 1008.5 MPa. This study widens the possibility of manufacturing ceramic 3D-printed objects with complex shapes, remarkable strength, and unique functionality, enabling their application in various industrial fields.
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