The polypropylene/ethylene-1-octene/short glass fiber (PP/EOC/SGF) ternary composites were prepared by extrusion and subsequent injection processes. The effects of compatilizers, including maleic anhydride grafted PP (PP-g-MAH) and maleic anhydride grafted EOC (EOC-g-MAH), on the evolution of phase structures and mechanical properties of PP composites were examined. Results show that the interfacial adhesion between SGF and matrix are enhanced significantly. Moreover, the EOC-g-MAH promotes to form the elastomeric particle-embedded configuration. Mechanical testing reveals that the PP/EOC/SGF composites characterized by much higher impact toughness and keeping the competitively tensile properties could be obtained through co-incorporation of SGF and EOC as well as right compatilizers adopted.
The short glass fiber (SGF)/polypropylene (PP) composites were prepared by extrusion and subsequently injection processes. The evolution of phase structures and mechanical properties of SGF/PP composites were performed using scanning electron microscopy (SEM), contact angle tensiometer, universal testing machine and impact tester. The results show that the interfacial adhesion between SGF and matrix were enhanced significant with the presence of maleic anhydride grafted PP (PP-g-MAH) and maleic anhydride grafted ethylene-1-octene copolymer (EOC-g-MAH). Moreover, the EOC-g-MAH promoted to form the novel configuration of EOC-g-MAH particles adhered firmly onto SGF surfaces, which resulted in the much higher impact toughness and tensile strength.
To improve the impact toughness of short glass fiber (SGF) reinforced polypropylene (PP) composite foams, maleic anhydride grafted ethylene-α-octene copolymer (mEOC) was employed as impact modifier and interfacial compatibilizer. And for comparison, mEOC was also introduced into PP/EOC/SGF composite foams. Then, the foaming qualities, interfacial structures and mechanical properties of samples against varying mEOC contents were examined and compared in detail. Results showed that adequate mEOC significantly improved the foamabilities of the composites, while the optimized mass fraction was 8% for PP/SGF composite foams and 3% for PP/EOC/SGF system. Increased mEOC facilitated the higher impact toughness, which was increased by 77% for PP/SGF composite foams, whereas only 5% for PP/EOC/SGF foams. However, the flexural strengths were just improved slightly, while compressive strengths decreased monotonically with mEOC for the investigated composite foams.
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