Please cite this article as: J.P. Díaz, I.P. Reyes, M.J. Taherzadeh, I.S. Horváth, M. Lundin, Anaerobic co-digestion of solid slaughterhouse wastes with agro-residues: Synergistic and antagonistic interactions determined in batch digestion assays, Chemical Engineering Journal (2014), doi: http://dx.doi.org/10. 1016/j.cej.2014.02.008 This is a PDF file of an unedited manuscript that has been accepted for publication. As a service to our customers we are providing this early version of the manuscript. The manuscript will undergo copyediting, typesetting, and review of the resulting proof before it is published in its final form. Please note that during the production process errors may be discovered which could affect the content, and all legal disclaimers that apply to the journal pertain.
AbstractDifferent mixture ratios of solid cattle slaughterhouse wastes (SB), manure (M), various crops (VC), and municipal solid wastes (MSW) were investigated for biogas production. The objective was to explore possible significant synergistic effects obtained from the combination of these different substrates. The performance of the process was assessed in thermophilic anaerobic batch co-digestion assays, using a four factor mixture design and methane yield (Y CH4 ) and specific methane production rate (r sCH4 ) as response variables.The highest methane yield, 655 NmL CH 4 /g VS was obtained when equal parts (ww) of SB, M, VC, and MSW were combined, while the combination of SB, M, and MSW resulted in the highest specific methane production rate (43 NmL CH 4 /g VS/d). A mixture design model was fitted to data in order to appraise synergistic and antagonistic interactions. Mixing all four substrates resulted in a 31% increase of the expected yield which was calculated from the methane potential of the individual fractions, clearly demonstrating a synergistic effect due to more balanced nutrient composition enhancing the anaerobic digestion process. However, no significant antagonistic effects were observed. In order to maximize both response variables simultaneously, a response surface method was employed to establish the optimal combination of substrate mixtures. The statistical results and analysis of the biological process gave a coherent picture of the results.
A co-digestion process was evaluated when mixing different ratios of agro-industrial residues, i.e. bovine slaughterhouse waste (SB); cow manure (M); various crop residues (VC); and municipal solid waste (MSW) by anaerobic batch digestion under thermophilic conditions (55 °C). A selected study case at mesophilic condition (37 °C) was also investigated. The performance of the co-digestion was evaluated by kinetics (k(0)). The best kinetic results were obtained under thermophilic operation when a mixture of 22% w/w SB, 22% w/w M, 45% w/w VC and 11% w/w MSW was co-digested, which showed a proper combination of high values in r(s)CH(4) and k(0) (0.066 Nm(3)CH(4)/kgVS*d, 0.336 d(-1)) during the anaerobic process. The effect of temperature on methane yield (Y(CH4)), specific methane rate (r(s)CH(4)) and k(0) was also analyzed for a specific study case; there a mixture of 25% w/w of SB, 37.5% w/w of M, 37.5% of VC and 0% of MSW was used. Response variables were severely affected by mesophilic conditions, diminishing to at least 45% of the thermophilic values obtained for a similar mixture. The effect of temperature suggested that thermophilic conditions are suitable to treat these residues.
scite is a Brooklyn-based organization that helps researchers better discover and understand research articles through Smart Citations–citations that display the context of the citation and describe whether the article provides supporting or contrasting evidence. scite is used by students and researchers from around the world and is funded in part by the National Science Foundation and the National Institute on Drug Abuse of the National Institutes of Health.