We report that self-sorting during self-organizing surface-initiated copolymerization (co-SOSIP) provides facile access to oriented multicomponent architectures. Alternate lateral and uniform axial self-sorting into formal supramolecular n/p-heterojunction photosystems is found to generate up to 40 times more photocurrent. More or less topological matching gives rise to alternate axial self-sorting into inactive charge-transfer complexes or uniform lateral sorting into the less active macrodomains, respectively. Experimental support for self-repair during co-SOSIP is reported. Initiators on the surface are shown to serve as templates for the self-sorting into multichannel architectures of freely variable composition.
Dithienylhexafluorocyclopentene with (R)- or (S)-N-phenylethylamide substituents formed rod-like and 0.2-1.0 microm-thick platelike crystals by sublimation; upon UV irradiation, the crystals bent concavely to the incident light and finally rolled crystals were obtained; the bent crystals were reconverted to flat crystals by visible light irradiation.
A combined theoretical and experimental study was performed on
diarylethenes and diarylethene-capped sexithiophenes aiming at an
improved understanding of the electrochemical and photochemical ring-opening
and ring-closing mechanisms. Theoretical calculations, based on DFT
and TDDFT, suggested that the spatial distribution and the occupancy
of the frontier orbitals determine and control the diarylethenes’
ring-opening and ring-closing upon photoirradiation and electrochemical
oxidation. Optimized geometries, potential energy surfaces, and activation
energies between the open-ring and closed-ring forms were calculated
for diarylethenes in the neutral ground state, excited states, and
mono- and dicationic states. Analysis of the frontier orbitals was
employed to understand the cyclization and cycloreversion of diarylethenes
and to predict and explain the switching properties of diarylethene-capped
sexithiophene molecular wires. The TDDFT data were verified with experimentally
measured UV/vis spectra. The DFT calculations estimated open-shell
ground states of diarylethene-capped sexithiophene dications, which
were verified with EPR spectroscopy, and the broadening of the peaks
in the EPR spectra were explained with the calculated singlet−triplet
splitting. The good agreement of experiment and theory allows for
the understanding of switching behavior of diarylethenes in solutions,
in metal break junctions, in monolayers on metal surfaces, and as
a part of complex organic molecular wires.
Photo-and electro-chromism of diarylethene modified ITO electrodes -towards molecular based read-write-erase information storage Areephong, J.; Browne, Wesley; Katsonis, N.; Feringa, B.L. Link to publication in University of Groningen/UMCG research database Citation for published version (APA): Areephong, J., Browne, W. R., Katsonis, N., & Feringa, B. L. (2006). Photo-and electro-chromism of diarylethene modified ITO electrodes -towards molecular based read-write-erase information storage.
The synthesis and photochemical characterization of bicomponent molecular switches based on covalently tethered dithienylethene photochromes is described. Both photochromic units undergo complete switching between the fully cyclised and fully non-cyclised states despite a significant level of electronic communication between the individual units and their proximity.
The photochemical and electrochemical properties of self-assembled monolayers (SAM) of three structurally distinct hexahydro-and hexafluoro-dithienylcyclopentene-based photochromic switches on gold electrodes are reported. The photochemical and electrochemical switching between the open and closed forms of the dithienylethene SAMs is examined and found to be sensitive to the molecular structure of the switch. For the three dithienylethenes, the electrochemical behavior with respect to electrochemical ring opening/closing is retained in the SAMs. In contrast, a marked dependence on the nature of the anchoring group is observed upon immobilization in terms of the retention of the photochemical properties observed in solution. For the meta-thiophenol anchor both photochemical ring opening and closing are observed in the SAM, while for the thienyl-thiol-anchored switches the photochemically properties are changed markedly compared with those observed in solution. The stability of the monolayers toward desorption following photochemical and electrochemical switching is examined through electrochemistry and X-ray photoelectron spectroscopy.
The interesting structural, electronic, and optical properties of DNA provide fascinating opportunities for developing nanoscale smart materials by integrating DNA with opto-electronic components. In this article we demonstrate the electrostatic binding of an amine-terminated dithienylethene (DET) molecular switch to double-stranded synthetic polynucleotides. The DET switch can undergo photochemical ring-closure and opening reactions. Circular dichroism (CD) and UV-vis spectroscopy show that both the open, 1o, and the closed, 1c, forms of the switch bind to DNA. Upon addition of DNA to a solution of 1o or 1c, the UV-vis spectrum displays a hypochromic effect, indicative of an interaction between the switch and the DNA. The chirality of the DNA double-helix is transmitted to the switching unit which displays a well-defined CD signal upon supramolecular complexation to the DNA. Additionally, the CD signal of the DNA attenuates, demonstrating that both components of the complex mutually influence each other's structure; the DNA induces chirality in the switch, and the switch modifies the structure of the DNA. Modulation of the chiroptical properties of the complex is achieved by photochemically switching the DET between its ring open and closed isomers. A pH dependence study of the binding shows that when the pH is increased the switches lose their binding ability, indicating that electrostatic interactions between protonated amines and the negatively charged phosphate backbone are the dominant driving force for binding to the DNA. A comparison of poly(deoxyguanylic-deoxycytidylic) acid [poly(dGdC)(2)] polynucleotides with poly(deoxyadenylic-deoxythymidylic) acid [poly(dAdT)(2)] shows distinct differences in the CD spectra of the complexes.
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