This review focuses on the available experimental and theoretical investigations on noble gas (Ng) endohedral fullerenes, addressing the effects of confinement of one or more Ng atoms into the electronic structure and reactivity of fullerenes.
After an exhaustive exploration of the potential energy surface of B12E- and B12E2 (E=Li-Cs) systems, it was found that, for the anionic series, a cage-type and a quasi-planar structure, very...
This work describes the use of C–H⋯F–C contacts in the solid-state from the stator towards the rotator to fine-tune their internal motion, by constructing a set of interactions that generate close-fitting cavities in three supramolecular rotors 1–3I.
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