Hydrogels are a class of soft material that is exploited in many, often completely disparate, industrial applications, on account of their unique and tunable properties. Advances in soft material design are yielding next-generation moldable hydrogels that address engineering criteria in several industrial settings such as complex viscosity modifiers, hydraulic or injection fluids, and sprayable carriers. Industrial implementation of these viscoelastic materials requires extreme volumes of material, upwards of several hundred million gallons per year. Here, we demonstrate a paradigm for the scalable fabrication of self-assembled moldable hydrogels using rationally engineered, biomimetic polymer-nanoparticle interactions. Cellulose derivatives are linked together by selective adsorption to silica nanoparticles via dynamic and multivalent interactions. We show that the self-assembly process for gel formation is easily scaled in a linear fashion from 0.5 mL to over 15 L without alteration of the mechanical properties of the resultant materials. The facile and scalable preparation of these materials leveraging self-assembly of inexpensive, renewable, and environmentally benign starting materials, coupled with the tunability of their properties, make them amenable to a range of industrial applications. In particular, we demonstrate their utility as injectable materials for pipeline maintenance and product recovery in industrial food manufacturing as well as their use as sprayable carriers for robust application of fire retardants in preventing wildland fires.hydrogels | manufacturing | nanotechnology | industrial applications | supramolecular I ndustrial settings present many unique and complicated engineering challenges. Inefficiencies arise in manufacturing because large volumes of material need to be pumped from one location to another and vast lengths of pipe of varying diameters must be cleaned frequently (1). Applications as diverse as hydraulic fracturing and cosmetics rely on processable fluids with complex viscoelastic properties. Moreover, many products and coatings are applied through spraying, which often requires uniform application and tunable retention of solvent and/or product. The advent of macromolecular chemistry has provided myriad polymeric materials that are used in diverse applications, including as food/cosmetic additives and viscosity modifiers. Several aqueous-based applications have exploited covalently cross-linked hydrogels, which comprise a class of soft materials that bind and retain large amounts of water and exhibit broadly tunable mechanical properties. However, the irreversibility of their cross-links is severely limiting and many applications would benefit enormously from new technologies allowing for stimuliresponsive aqueous viscosity modification and/or the ability to rearrange their shape in response to applied stress (2).Recent advances in supramolecular chemistry and materials science are enabling unique solutions to many critical industrial challenges via the production of mo...
SignificanceDespite strong fire prevention efforts, every year wildfires destroy millions of acres of forest. While fires are necessary for a healthy forest ecology, the vast majority are human-caused and occur in high-risk areas such as roadsides and utilities infrastructure. Yet, retardant-based treatments to prevent ignitions at the source are currently impossible with existing technologies, which are only suited for reactive fire prevention approaches. Here we develop a viscoelastic carrier fluid for existing fire retardants to enhance retention on common wildfire-prone vegetation through environmental exposure and weathering. These materials enable a prophylactic wildfire prevention strategy, where areas at high risk of wildfire can be treated and protected from ignitions throughout the peak fire season.
A preventative treatment of fire retardants at high-risk locales can potentially stop a majority of wildfires. For example, over 80% of wildfire ignitions in California occur at high-risk locales such as adjacent to roadsides and utility infrastructure. Recently a new class of ammonium polyphosphate retardants was developed with enhanced adherence and retention on vegetation to enable prophylactic treatments of these high-risk locals to provide season-long prevention of ignitions. Here, we compare three different ammonium (poly)phosphate-based wildland retardant formulations and evaluate their resistance to weathering and analyze their seasonal impact on soil chemistry following application onto grass. Soil samples from all three treatments demonstrated no changes in soil pH and total soil carbon and nitrogen amounts. Total soil phosphorus amounts increased by ∼2−3× following early precipitation, always remaining within typical topsoil amounts, and returned to the same level as control soil before spring. Available indices of ammonium, nitrate, and phosphate levels for all groups were elevated compared to the untreated control samples, again remaining within typical topsoil ranges across all time points and rainfall amounts evaluated. Microbial activity was decreased, potentially because the addition of available nutrients from retardant application reduced the need for organic decomposition. These results demonstrate that the application of ammonium (poly)phosphate-based retardants does not alter soil chemistry beyond typical topsoil compositions and are thus suitable for use in prophylactic wildfire prevention strategies.
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