Agricultural soil erosion is thought to perturb the global carbon cycle, but estimates of its effect range from a source of 1 petagram per year −1 to a sink of the same magnitude. By using caesium-137 and carbon inventory measurements from a large-scale survey, we found consistent evidence for an erosion-induced sink of atmospheric carbon equivalent to approximately 26% of the carbon transported by erosion. Based on this relationship, we estimated a global carbon sink of 0.12 (range 0.06 to 0.27) petagrams of carbon per year −1 resulting from erosion in the world's agricultural landscapes. Our analysis directly challenges the view that agricultural erosion represents an important source or sink for atmospheric CO 2 .
Radioactive fallout 137Cs (cesium‐137) deposited across the landscape from atmospheric nuclear tests is strongly absorbed on soil particles limiting its movement by chemical and biological processes. Most 137Cs movement in the environment is by physical processes; therefore, 137Cs is a unique tracer for studying erosion and sedimentation. Cesium‐137 loss from a watershed has been shown to correlate strongly with soil loss calculated by the Universal Soil Loss Equation (USLE) or measured from small runoff plates. By measuring spatial patterns of 137Cs in vertical and horizontal planes across the landscape, rates of soil loss or deposition can be measured for different parts of a watershed. Even within landscape units, redistribution of soil can be mapped and erosion or deposition rates for different parts of individual fields measured and mapped. Sediment accumulation rates can be measured by comparing the vertical distribution of 137Cs in sediments with the temporal deposition of fallout 137Cs from the atmosphere to locate sediment horizons. Using these dated sediment horizons, sediment accumulation rates can be measured. Interpretations about the location of these dated horizons must consider particle size of the sediments, reworking of deposited sediments, diffusional movement of 137Cs, and time rates of physical process in the sedimentation process. The 137Cs technique can be used to determine sediment accumulation rates in a wide variety of depositional environments including reservoirs, lakes, wetlands, coastal areas, and floodplains. The bibliography shows that 137Cs has been used widely for studying erosion and sedimentation in many different environments around the world.
Remote sensing techniques can be used to monitor water quality parameters (i.e., suspended sediments (turbidity), chlorophyll, and temperature). Optical and thermal sensors on boats, aircraft, and satellites provide both spatial and temporal information needed to monitor changes in water quality parameters for developing management practices to improve water quality. Recent and planned launches of satellites with improved spectral and spatial resolution sensors should lead to greater use of remote sensing techniques to assess and monitor water quality parameters. Integration of remotely sensed data, GPS, and GIS technologies provides a valuable tool for monitoring and assessing waterways. Remotely sensed data can be used to create a permanent geographically located database to provide a baseline for future comparisons. The integrated use of remotely sensed data, GPS, and GIS will enable consultants and natural resource managers to develop management plans for a variety of natural resource management applications.
The biocides triclosan and triclocarban are wastewater contaminants whose occurrence and fate in estuarine sediments remain unexplored. We examined contaminant profiles in 137 Cs/ 7 Be-dated sediment cores taken near wastewater treatment plants in the Chesapeake Bay watershed (CB), Maryland and Jamaica Bay (JB), New York. In JB, biocide occurrences tracked the time course of biocide usage and wastewater treatment strategies employed, first appearing in the 1950s (triclocarban) and 1960s (triclosan), and peaking in the late 1960s and 1970s (24 ± 0.54 and 0.8 ± 0.4 29 mg/kg dry weight, respectively). In CB, where time of sediment accumulation was not as well constrained by 137 Cs depth profiles, triclocarban was only measurable in 137 Cs bearing sediments, peaking at 3.6 ± 0.6 mg/kg midway through the core and exceeding 1 mg/kg in recent deposits. In contrast, triclosan concentrations were low or not detectable in the CB core. Analysis of CB sediment by tandem mass spectrometry produced the first evidence for complete sequential dechlorination of triclocarban to the transformation products dichloro-, monochloro-, and unsubstituted carbanilide which were detected at maxima of 15.5 ± 1.8, 4.1 ± 2.4, and 0.5 ± 0.1 mg/kg, respectively. Concentrations of all carbanilide congeners combined were correlated with heavy metals (R 2 > 0.64, P<0.01), thereby identifying wastewater as the principal pathway of contamination. Environmental persistence over the past 40 years was observed for triclosan and triclocarban in JB, and for triclocarban and its diphenylurea backbone in CB sediments.
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