Long-term experiments have been carried out to investigate the impact of Nickel (Ni) coarsening on the performance of Solid Oxide Cell. Durability tests have been performed with H2 electrode supported cells at 850 °C and 750 °C in fuel cell and electrolysis modes. Microstructural changes in the composite electrode of Nickel and Yttria Stabilized Zirconia (YSZ) have been characterized by synchrotron X-ray nanotomography. Analysis of the reconstructions have revealed that Ni coarsening induces a significant decrease of both the density of Triple Phase Boundary lengths (TPBls) and the Ni/gas specific surface area. However, the contact surface between Ni and YSZ is not changed upon operation, meaning the Ni sintering is inhibited by the YSZ backbone. Moreover, the Ni coarsening rate is independent of the electrode polarization. The evolution of TPBls in operation has been fitted by a phenomenological law implemented in an electrochemical model. Simulations have shown that microstructural changes in the H2 electrode explain 30% of the total degradation in fuel cell mode and 25% in electrolysis mode at 850 °C after 1000-2000 h. Moreover, it has been highlighted that the temperature at which the degradation is estimated after the durability experiment plays a major role on the result.
Abstract. An original 3D stochastic model, based on the truncated plurigaussian random fields, has been adapted to simulate the complex microstructure of SOC electrodes. The representativeness of the virtual microstructures has been checked on several synchrotron Xray and FIB-SEM tomographic reconstructions obtained on typical LSCF, LSC and Ni-YSZ electrodes. The validation step has been carried out by comparing numbers of electrode morphological properties as well as the phase effective diffusivities. This analysis has shown that the synthetic media mimic accurately the complex microstructure of typical SOC electrodes. The model capability to simulate different types of promising electrode architectures has also been investigated. It has been shown that the model is able to generate virtual electrode prepared by infiltration resulting in a uniform and continuous thin layer covering a scaffold.With a local thresholding depending on the position, continuous graded electrodes can be also produced. Finally, the model offers the possibility to introduce different correlation lengths for each phase in order to control the local topology of the interfaces. All these cases illustrate the model flexibility to generate various SOC microstructures. This validated and flexible model can be used for further numerical microstructural optimizations to improve the SOC performances.Keyword: Solid Oxide Cell, 3D microstructure model, truncated plurigaussian random fields, X-ray tomography, Electrode design.
Two types of solid oxide cells with different Ni-YSZ cermet microstructures have been aged in electrolysis and fuel cell modes for operating times ranging from 1000 to 15000 hours. The pristine and aged cermets have been reconstructed by synchrotron X-ray holotomography. Nickel agglomeration has been observed in the bulk of the operated samples inducing a significant loss of triple phase boundary lengths. The inspection of the microstructural properties has confirmed the stabilizing role of YSZ on Ni coarsening. Furthermore, the gradients of properties quantified at the electrolyte interface have revealed a depletion of Ni only in the electrochemically active region of the electrode. The process is strongly promoted for a coarse cermet microstructure when operated under electrolysis current. The evolution of the microstructural properties has been implemented in an in-house multiscale model. The simulations have shown that the loss of performance is dominated by the depletion of Ni in case of a coarse microstructure. Thanks to the computations, it has been shown that the Ni depletion is controlled by the cathodic overpotential. To explain this dependency, it has been proposed that the accumulation of oxygen vacancies in the double layer could deteriorate the Ni/YSZ interface and trigger the Ni depletion.
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