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Abstract:The proper assessment of design flood is a major concern for many hydrological applications in small urban watersheds. A number of approaches can be used including statistical approach and the continuous simulation and design storm methods. However, each method has its own limitations and assumptions being applied to the real world. The design storm method has been widely used for a long time because of the simplicity of the method, but three critical assumptions are made such as the equality of the return periods between the rainfall and corresponding flood quantiles and the selections of the rainfall hyetograph and antecedent soil moisture conditions. Continuous simulation cannot be applied to small urban catchments with quick responses of runoff to rainfall. In this paper, a new flood frequency analysis for the simulated annual peak flows (FASAP) is proposed. This method employs the candidate rainfall events selected by considering a time step order of five minutes and a sliding duration without any assumptions about the conventional design storm method in an urban watershed. In addition, the proposed methodology was verified by comparing the results with the conventional method in a real urban watershed. OPEN ACCESSWater 2014, 6 3842 Keywords: design storm method; continuous simulation method; flood frequency analysis; urban drainage basin

In this work, we study the interlayer interactions between sheets of blue phosphorus with quantum Monte Carlo (QMC) methods. We find that as previously observed in black phosphorus, interlayer binding of blue phosphorus cannot be described by van der Waals (vdW) interactions alone within the density-functional theory framework. Specifically, while some vdW density functionals produced reasonable binding curves, none of them could provide a correct, even qualitatively, description of charge redistribution due to interlayer binding. We also show that small systematic errors in common practice QMC calculations, such as the choice of optimized geometry and finitesize corrections, are non-negligible given the energy and length scales of this problem. We mitigate some of the major sources of error and report QMC-optimized lattice constant, stacking, and interlayer binding energy for blue phosphorus. It is strongly suggested that these considerations are important and quite general in the modeling of two-dimensional phosphorus allotropes.

Structural properties and energetics of carbon rings are studied with the diffusion Monte Carlo (DMC) method. Our DMC-based geometry optimization reveals that both polyynic C 4n and cumulenic C 4n + 2 rings exhibit bond length alternations for n ≥ 3, which is understood to be due to Jahn−Teller distortions. The bond length alternation even in a cumulenic (4n + 2) carbon ring was experimentally observed in a recently synthesized C 18 molecule. From a comparison of the DMC cohesive energies of C 4n with those of C 4n + 2 , we present a comprehensive picture of the competition between Huckel's rule and Jahn−Teller distortion in small carbon rings; the former is more dominant than the latter for n < 5 where C 4n + 2 rings are more stable than C 4n , while C 4n rings are as stable as C 4n + 2 for n < 5 where dimerization effects due to Jahn−Teller distortion are more important.

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