This study was conducted to investigate the effects of deep eutectic solvent (DES) treatment on BCTMP fibers and handsheets properties. DES was prepared using lactic acid and betaine (LB), and the molar ratio of these two components mixtures was controlled to 2:1 (LB 2:1) and 5:1 (LB 5:1). As results, 2% of BCTMP pulp (o.d. weight) was extracted when it was treated by LB 5:1 at 50℃ for 12 hours, stirring constantly at 120 rpm. In contrast, lignin was not extracted when BCTMP was mildly treated by the LB DES mixed with 50% of distilled water at the reacting condition of temperature 60℃ for 2 hours using water bath. These results indicate that conditioned water content and adequate reaction time are needed to achieve effective extraction of lignin. It was also found that stiffening of cellulose fiber due to the mild treatment of LB DES to BCTMP fiber leads to the increase of paper bulk without the loss of strength.
This study was conducted to investigate the effects of deep eutectic solvent (DES) treatment on properties of TMP fibers and handsheets. DES was prepared by mixing of lactic acid and betaine (L and B), and the molar ratio of these two components mixtures was controlled to 2:1 (L:B=2:1) and 5:1 (L:B=5:1). As results, lignin was partly extracted from the TMP fibers. Especially, the delignification of TMP samples was promoted according to the increase of the molar ratio of lactic acid. Except for tear index, both tensile index and burst index of handsheets were increased when higher molar ratio of lactic acid was mixed for DES preparation. However, the LB DES treatment of TMP fibers didn't give any effect on the optical properties of TMP handsheets. The plausibility of TMP fiber was to be enhanced by LB DES treatment.
Disposable diaper has been used in order to handle urine and feces conveniently. At present the amount of disposable diaper waste increases gradually. Incineration and landfill have been the only ways to dispose of disposable diapers. However, if they are disposed by landfill, decomposition will take more than one hundred years. In addition, another way of dispose incineration has caused air pollution. Therefore, it is necessary to study recycling process for disposable diaper since plastic and wood fibers of diaper are useful materials to recycle. In this study, pulping condition of disposable diaper waste was studied in order to effectively separate the components. Recovery rates of plastic and fibers were analyzed under different pulping conditions. It was found that optimum pulping consistency was 5%, time was 60 minutes, temperature was 50°C, and cut size is 21 cm×21 cm. The recovery rate of plastic and fibers can be achieved above 70% under the optimum pulping condition.
Gas
grafting with fatty acid chloride (FAC) is a simple and ultrafast
paper treatment, which produces only hydrochloric acid as a byproduct.
In this study, poly(vinyl alcohol) (PVOH)-coated paper was treated
by gas grafting with palmitoyl chloride, and the effects of temperature,
time, and concentration of palmitoyl chloride on discoloration were
investigated. The grafting efficiency expressed by the water absorption
capacity (Cobb size) and the amount of grafted FAC increased with
increasing temperature, reaction time, and concentration of palmitoyl
chloride. However, discoloration of PVOH was inevitable at high temperature
and long reaction time, and under excessive FAC dosage. PVOH was converted
into polyene via dehydration by the acid catalyst at high temperature.
Calcium carbonate applied to PVOH coating for preventing discoloration
of the PVOH-coated paper could neutralize gaseous hydrochloric acid.
Unfortunately, the hydrophobicity decreased slightly with an increase
in the calcium carbonate blending ratio due to the additional consumption
of FAC. The grafting efficiency could be improved without discoloration
if the blending ratio was appropriately controlled based on the specific
surface area of the calcium carbonate particles.
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