PACS 45.70.-n -Granular systems PACS 47.57.-s -Complex fluids and colloidal systems PACS 61.50.Ah -Theory of crystal structure, crystal symmetry; calculations and modelingAbstract -A line of hard spheres confined by a transverse harmonic potential, with hard walls at its ends, exhibits a variety of buckled structures as it is compressed longitudinally. Here we show that these may be conveniently observed in a rotating liquid-filled tube (originally introduced by Lee et al. [T. Lee, K. Gizynski, and B. Grzybowski, Adv. Mater. 29, 1704274 (2017)] to assemble ordered three dimensional structures at higher compressions). The corresponding theoretical model is transparent and easily investigated numerically, as well as by analytic approximations. Hence we explore a wide range of predicted structures occurring via bifurcation, of which the stable ones are also observed in our experiments. Qualitatively similar structures have previously been found in trapped ion systems.
Jammed soft matter systems are often modelled as dense packings of overlapping soft spheres, thus ignoring particle deformation. For 2D (and 3D) soft disks packings, close to the critical packing fraction φ c , this results in an increase of the average contact number Z with a square root in φ − φ c . Using the program PLAT, we find that in the case of idealised two-dimensional foams, close to the wet limit, Z increases linearly with φ − φ c , where φ is the gas fraction. This result is consistent with the different distributions of separations for soft disks and foams at the critical packing fraction. Thus, 2D foams close to the wet limit are not well described as random packings of soft disks, since bubbles in a foam are deformable and adjust their shape. This is not captured by overlapping circular disks.
There is a growing interest in cylindrical structures of hard and soft particles. A promising new method to assemble such structures has recently been introduced by Lee et al. [T. Lee, K. Gizynski, and B. Grzybowski, Adv. Mater. 29, 1704274 (2017)]. They used rapid rotation around a central axis to drive spheres of lower density than the surrounding fluid towards this axis. This resulted in different structures as the number of spheres is varied. Here we present comprehensive analytic energy calculations for such self-assembled structures, based on a generic soft sphere model, from which we obtain a phase diagram. It displays interesting features, including peritectoid points. These analytic calculations are complemented by preliminary numerical simulations for finite sample sizes with soft spheres. A similar analytic approach could be used to study packings of spheres inside cylinders of fixed dimensions, but with a variation in the number of spheres.
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