Martian meteorites and terrestrial analogs represent the only samples available on Earth for studying mineralogy features of our neighbor planet Mars. This work characterizes the Roberts Massif (RBT) 04262 Martian meteorite by using mainly Raman spectroscopy. By means of this technique, it was confirmed that the meteorite matrix is composed by pyroxene and plagioclase (converted to maskelynite due to the shock pressure). Olivine-coarse grains embedded in the matrix were also observed. These grains were coated by hydrated magnesium and calcium sulfates, which would belong to the Mars sulfate deposits or to the terrestrial weathering. Although the sulfates could be formed on Mars due to the oxidation of sulfides or elemental sulfur along the sulfur Mars cycle, their distribution along cracks and fractures confirm that are weathering products. However, other S-bearing compounds that belong to Mars were found, such as elemental sulfur and a thermally transformed iron sulfide.Finally, the calcium phosphate merrillite and titanomagnetite were also detected. Taking this into account, the minerals found were classified into primary minerals that belong to Mars (pyroxene, olivine, elemental sulfur, and titanomagnetite), secondary ones that are alteration products of the primary minerals (maskelynite, iron sulfide, and merrillite), and terrestrial weathering products (sulfates gypsum and epsomite).
Martian soils are critically important for understanding the history of Mars, past potentially habitable environments, returned samples, and future human exploration. This paper examines soil crusts on the floor of Jezero crater encountered during initial phases of the Mars 2020 mission. Soil surface crusts have been observed on Mars at other locations, starting with the two Viking Lander missions. Rover observations show that soil crusts are also common across the floor of Jezero crater, revealed in 45 of 101 locations where rover wheels disturbed the soil surface, 2 out of 7 helicopter flights that crossed the wheel tracks, and 4 of 8 abrasion/drilling sites. Most soils measured by the SuperCam laser‐induced breakdown spectroscopy (LIBS) instrument show high hydrogen content at the surface, and fine‐grained soils also show a visible/near infrared (VISIR) 1.9 µm H2O absorption feature. The Planetary Instrument for X‐ray Lithochemistry (PIXL) and SuperCam observations suggest the presence of salts at the surface of rocks and soils. The correlation of S and Cl contents with H contents in SuperCam LIBS measurements suggests that the salts present are likely hydrated. On the “Naltsos” target, magnesium and sulfur are correlated in PIXL measurements, and Mg is tightly correlated with H at the SuperCam points, suggesting hydrated Mg‐sulfates. Mars Environmental Dynamics Analyzer (MEDA) observations indicate possible frost events and potential changes in the hydration of Mg‐sulfate salts. Jezero crater soil crusts may therefore form by salts that are hydrated by changes in relative humidity and frost events, cementing the soil surface together.
A lunar feldspathic breccia meteorite,
the Northwest Africa (NWA)
11273, was analyzed to compensate the lack of scientific data available
about its mineralogy and geochemistry. In order to obtain a deeper
characterization of the sample, a strategy based on the combination
of nondestructive spectroscopic techniques such as X-ray fluorescence
and Raman spectroscopy is used. Both techniques are being used in
spatial missions by the Perseverance Rover, so their combination in
the laboratory is here proposed as an optimal strategy to study the
complete mineralogy of the sample. In addition to finding the minerals
indicated by the Meteoritical Society (anorthite, olivine, pyroxene,
kamacite, and troilite), other minor minerals were identified, such
as zircon and ilmenite, which are minerals related to the Moon geology,
as well as calcite and sulfate which can be considered products of
terrestrial weathering. Finally, secondary minerals related to alteration
processes were also found, such as hematite, quartz, and anatase.
In this work, the alteration processes that gave rise to the detected
secondary minerals have been proposed.
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